A pathway of the generation of acid mine drainage and release of arsenic in the bioleaching of orpiment
文献类型：期刊论文
| 作者 | Shen, Cailong2,3; Zhang, Guangji2,3; Li, Kexin1; Yang, Chao2,4 |
| 刊名 | CHEMOSPHERE
 |
| 出版日期 | 2022-07-01 |
| 卷号 | 298页码:8 |
| ISSN号 | 0045-6535 |
| 关键词 | Orpiment Bioleaching Arsenic contamination Acid production pH dependence |
| DOI | 10.1016/j.chemosphere.2022.134287 |
| 英文摘要 | Arsenic in acid mine drainage (AMD) is commonly associated with the bioleaching of arsenic sulfide minerals. Orpiment is iron free and one of the most common arsenic sulfide minerals, but no studies are involved with the relationship between the iron free bioleaching of orpiment and the generation of arsenic-containing AMD. In this study, the iron free bioleaching experiments with Acidithiobacillus thiooxidans (T.t) or Acidithiobacillus caldus (A.c) were carried out. In the experiments with T.t, the pH value decreased with time, and the leached arsenic increased significantly. Meanwhile, the density of planktonic bacteria increased gradually, suggesting that T.t survived in the orpiment pulp. However, in the experiments with initial pH of 1, pH changed little and arsenic was nearly not leached, implying that the bioleaching of orpiment can be inhibited when the initial pH was too low. The XRD patterns and the TFESEM-EDS analyses showed that no elemental sulfur was detected on the orpiment surface. It was supposed that the sulfur was converted to sulfuric acid in the bioleaching process. The CFESEM images showed that no corrosion pits were formed though a few cells adhered to the orpiment surface, and the TEM images showed that no extracellular polymeric substances (EPS) were excreted by the attached cells on the orpiment particles. In the experiments with A.c, similar results were obtained. It is inferred that the bioleaching of orpiment under iron deficient conditions in mining areas generates arsenic-containing AMD, but can be inhibited when the initial pH is too low. |
| WOS关键词 | ACIDITHIOBACILLUS-THIOOXIDANS ; THIOBACILLUS-FERROOXIDANS ; HYDROGEN-SULFIDE ; OXIDATION ; ARSENOPYRITE ; DISSOLUTION ; MECHANISMS ; REMOVAL ; AS2S3 ; H2S |
| 资助项目 | National Key R&D Program of China[2019YFC1904204] ; National Natural Science Foundation of China[21961160745] ; NSFC-EU project[31961133018] ; Key Research Pro-gram of Frontier Sciences of CAS, China[QYZDJ-SSW-JSC030] ; Chemistry and Chemical Engineering Guangdong Laboratory[1922006] |
| WOS研究方向 | Environmental Sciences & Ecology |
| 语种 | 英语 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| WOS记录号 | WOS:000795157800004 |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; NSFC-EU project ; Key Research Pro-gram of Frontier Sciences of CAS, China ; Chemistry and Chemical Engineering Guangdong Laboratory |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/53394]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Zhang, Guangji; Yang, Chao |
| 作者单位 | 1.China Univ Min & Technol Beijing, Sch Chem & Environm Engn, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China 4.Chem & Chem Engn Guangdong Lab, Shantou 515031, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen, Cailong,Zhang, Guangji,Li, Kexin,et al. A pathway of the generation of acid mine drainage and release of arsenic in the bioleaching of orpiment[J]. CHEMOSPHERE,2022,298:8. |
| APA | Shen, Cailong,Zhang, Guangji,Li, Kexin,&Yang, Chao.(2022).A pathway of the generation of acid mine drainage and release of arsenic in the bioleaching of orpiment.CHEMOSPHERE,298,8. |
| MLA | Shen, Cailong,et al."A pathway of the generation of acid mine drainage and release of arsenic in the bioleaching of orpiment".CHEMOSPHERE 298(2022):8. |
入库方式： OAI收割
来源：过程工程研究所
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