Ionic liquids as a tunable solvent and modifier for biocatalysis
文献类型：期刊论文
| 作者 | Li, Zhuang1,2; Han, Qi3; Wang, Kun1; Song, Shaoyu1; Xue, Yaju1; Ji, Xiuling1; Zhai, Jiali3; Huang, Yuhong1,4,5; Zhang, Suojiang1 |
| 刊名 | CATALYSIS REVIEWS-SCIENCE AND ENGINEERING
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| 出版日期 | 2022-06-01 |
| 页码 | 47 |
| ISSN号 | 0161-4940 |
| 关键词 | Ionic liquids ionic microenvironment biocatalysis homogeneous biocatalysis multiphasic biocatalysis enzyme immobilization |
| DOI | 10.1080/01614940.2022.2074359 |
| 英文摘要 | The use of biocompatible ionic liquids (bio-ILs) as a "green" solvent with uniquely tunable cations and anions, specific selectivity, and many other desirable physicochemical properties in biocatalysis has shown great promises to address many challenges. A plethora of studies have demonstrated ILs possess a range of exceptional capabilities in coordinating biocatalysis such as stabilizing enzyme structure, enhancing enzyme-substrate interaction, increasing substrate solubility and product separation/removal, and improving enzyme immobilization/recycling. Therefore, bio-ILs have been explored for biocatalysis in a wide range of homogenous as well as multiphasic systems including biphasic, multiphasic, microemulsion, and whole-cell systems. This review provides an overview of IL-enabled biocatalysis including enzymatic and whole-cell reactions in homogeneous and multiphasic systems. First, the properties of IL concentration, specific ion effect, pH, viscosity, alkyl chain length, hydrophobicity, and polarity on the structures and activities of enzymes are discussed together with characterization techniques to elucidate the mechanisms of IL-enzyme interactions. Second, while homogenous biocatalysis systems containing ILs are briefly introduced and summarized, particular attention is given to multiphasic systems. Furthermore, recent progress in using bio-ILs to modify emerging new enzyme carrier materials including carbonaceous and magnetic nanomaterials, gel microspheres, and membranes as well as their effect on increasing enzyme stability and recycling are highlighted. Finally, we provide our expert opinion for more innovative research in the field and future outlook for the industrial application of ILs in biocatalysis. |
| WOS关键词 | PENICILLIN-G ACYLASE ; MESOPOROUS SILICA SBA-15 ; MULTIWALLED CARBON NANOTUBES ; DEEP EUTECTIC SOLVENTS ; LIGNOCELLULOSIC BIOMASS ; LIPASE IMMOBILIZATION ; THERMAL-STABILITY ; COVALENT IMMOBILIZATION ; CATALYTIC PERFORMANCE ; POLYETHYLENE-GLYCOL |
| 资助项目 | National Key Research and Development Program[2021YFC2104200] ; National Natural Science Foundation of China[22078346] ; Dalian National Laboratory for Clean Energy (DNL) Cooperation Fund, CAS[DNL201909] ; Beijing Nova Program of Science and Technology[Z201100006820141] ; Beijing Nova Program of Science and Technology[Z211100002121164] ; Innovation Academy for Green Manufacture, CAS[IAGM2020C19] ; RMIT Research Fellowship |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | TAYLOR & FRANCIS INC |
| WOS记录号 | WOS:000803980500001 |
| 资助机构 | National Key Research and Development Program ; National Natural Science Foundation of China ; Dalian National Laboratory for Clean Energy (DNL) Cooperation Fund, CAS ; Beijing Nova Program of Science and Technology ; Innovation Academy for Green Manufacture, CAS ; RMIT Research Fellowship |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/53531]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Zhai, Jiali; Huang, Yuhong; Zhang, Suojiang |
| 作者单位 | 1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing, Peoples R China 3.RMIT Univ, STEM Coll, Sch Sci, 124 La Trobe St, Melbourne, Vic 3000, Australia 4.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing, Peoples R China 5.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Zhuang,Han, Qi,Wang, Kun,et al. Ionic liquids as a tunable solvent and modifier for biocatalysis[J]. CATALYSIS REVIEWS-SCIENCE AND ENGINEERING,2022:47. |
| APA | Li, Zhuang.,Han, Qi.,Wang, Kun.,Song, Shaoyu.,Xue, Yaju.,...&Zhang, Suojiang.(2022).Ionic liquids as a tunable solvent and modifier for biocatalysis.CATALYSIS REVIEWS-SCIENCE AND ENGINEERING,47. |
| MLA | Li, Zhuang,et al."Ionic liquids as a tunable solvent and modifier for biocatalysis".CATALYSIS REVIEWS-SCIENCE AND ENGINEERING (2022):47. |
入库方式： OAI收割
来源：过程工程研究所
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