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Measurement and Correlation of Solubility of Methyl 1,2,4-Triazole-3-carboxylate in 14 Pure Solvents from 278.15 to 318.15 K br

文献类型：期刊论文

作者Li, Yang1; Liu, Kejia1; Meng, Long1,2; Wang, Yong1,2
刊名JOURNAL OF CHEMICAL AND ENGINEERING DATA
出版日期2022-05-12
卷号67期号:5页码:1259-1266
ISSN号0021-9568
DOI10.1021/acs.jced.1c00957
英文摘要The solubility of methyl 1,2,4-triazole-3-carboxylatein 14 solvents (methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, isobutyl alcohol, acetonitrile, acetone, 2-pentanone, 3-pentanone, 4-methyl-2-pentanone, cyclopentanone, cyclohexa-none, tetrahydrofuran) in the range from 278.15 to 318.15 Kand at atmospheric pressure was measured in this study. Thesolubility of methyl 1,2,4-triazole-3-carboxylate in all solventsincreases with the increasing temperature. The solubility of methyl1,2,4-triazole-3-carboxylate in the solvents except for methanol andcyclohexanone does not show much difference, and is significantlysmaller than that in methanol and cyclohexanone. The solubility ofmethyl 1,2,4-triazole-3-carboxylate is not strictly related to polarityof the solvents as it is to the existence of other factors. The solubility of methyl 1,2,4-triazole-3-carboxylate was correlated by the lambda hequation, modified Apelblat model, and Yaws model. The Yaws model is the best one among the three models with average relativedeviation (ARD) and average root-mean-square deviation (104(RMSD)) of 1.18% and 0.364. The work in this study providesimportant solubility data for purification and synthesis of methyl 1,2,4-triazole-3-carboxylate.
WOS关键词THERMODYNAMIC PROPERTIES ; WATER ; MONOSOLVENTS ; MIXTURES
资助项目Self-deployed Projects of Ganjiang Innovation Academy, Chinese Academy of Sciences[E055A002] ; Jiangxi Province Key Laboratory of Cleaner Production of Rare Earths[E03MYB03] ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences[IAGM 2020DA02] ; Key Research Program of the Chinese Academy of Sciences[ZDRW-CN-2021-3-3]
WOS研究方向Thermodynamics ; Chemistry ; Engineering
语种英语
WOS记录号WOS:000803148500021
出版者AMER CHEMICAL SOC
资助机构Self-deployed Projects of Ganjiang Innovation Academy, Chinese Academy of Sciences ; Jiangxi Province Key Laboratory of Cleaner Production of Rare Earths ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences
源URL[http://ir.ipe.ac.cn/handle/122111/53535]  
专题中国科学院过程工程研究所
通讯作者Wang, Yong
作者单位1.Chinese Acad Sci, Ganjiang Innovat Acad, Ganzhou 341000, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714		 Li, Yang,Liu, Kejia,Meng, Long,et al. Measurement and Correlation of Solubility of Methyl 1,2,4-Triazole-3-carboxylate in 14 Pure Solvents from 278.15 to 318.15 K br[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2022,67(5):1259-1266.
APA Li, Yang,Liu, Kejia,Meng, Long,&Wang, Yong.(2022).Measurement and Correlation of Solubility of Methyl 1,2,4-Triazole-3-carboxylate in 14 Pure Solvents from 278.15 to 318.15 K br.JOURNAL OF CHEMICAL AND ENGINEERING DATA,67(5),1259-1266.
MLA Li, Yang,et al."Measurement and Correlation of Solubility of Methyl 1,2,4-Triazole-3-carboxylate in 14 Pure Solvents from 278.15 to 318.15 K br".JOURNAL OF CHEMICAL AND ENGINEERING DATA 67.5(2022):1259-1266.

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来源：过程工程研究所

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