Heterojunctioned CuO/Cu 2 O catalyst for highly efficient ozone removal
文献类型:期刊论文
作者 | Ma, Guojun1,2,3; Tang, Wenxiang4; Wang, Anqi1,2; Zhang, Le1,2; Guan, Jian1,2; Han, Ning1,2,3; Chen, Yunfa1,2,3 |
刊名 | JOURNAL OF ENVIRONMENTAL SCIENCES |
出版日期 | 2023-03-01 |
卷号 | 125页码:340-348 |
ISSN号 | 1001-0742 |
关键词 | Cu 2 O Ozone decomposition CuO Heterojunction |
DOI | 10.1016/j.jes.2022.01.0321001-0742 |
英文摘要 | In recent years, near surface ozone pollution, has attracted more and more attention, which necessitates the development of high efficient and low cost catalysts. In this work, CuO/Cu 2 O heterojunctioned catalyst is fabricated by heating Cu 2 O at high temperature, and is adopted as ozone decomposition catalyst. The results show that after Cu 2 O is heated at 180 ??C conversion of ozone increases from 75.2% to 89.3% at mass space velocity 1,920,000 cm 3 /(g ??hr) in dry air with 1000 ppmV ozone, which indicates that this heterojunction catalyst is one of the most efficient catalysts reported at present. Catalysts are characterized by electron paramagnetic resonance spectroscopy and ultraviolet photoelectron spectroscopy, which confirmed that the heterojunction promotes the electron transfer in the catalytic process and creates more defects and oxygen vacancies in the CuO/Cu 2 O interfaces. This procedure of manufacturing heterostructures would also be applicable to other metal oxide catalysts, and it is expected to be more widely applied to the synthesis of high-efficiency heterostructured catalysts in the future. ?? 2022 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V. |
WOS关键词 | CUPROUS-OXIDE ; CO OXIDATION ; AIR-POLLUTION ; BAND-GAP ; DECOMPOSITION ; CU2O ; TEMPERATURE ; XPS ; NANOSTRUCTURES ; DEGRADATION |
资助项目 | Chengdu Science and Technology Program[2019YF05-01833-SN] |
WOS研究方向 | Environmental Sciences & Ecology |
语种 | 英语 |
出版者 | SCIENCE PRESS |
WOS记录号 | WOS:000798821400016 |
资助机构 | Chengdu Science and Technology Program |
源URL | [http://ir.ipe.ac.cn/handle/122111/53619] |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Han, Ning; Chen, Yunfa |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Key Lab Sci & Technol Particle Mat, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Ctr Excellence Reg Atmospher Environm, Inst Urban Environm, Xiamen 361021, Peoples R China 4.Sichuan Univ, Sch Chem Engn, Chengdu 610065, Peoples R China |
推荐引用方式 GB/T 7714 | Ma, Guojun,Tang, Wenxiang,Wang, Anqi,et al. Heterojunctioned CuO/Cu 2 O catalyst for highly efficient ozone removal[J]. JOURNAL OF ENVIRONMENTAL SCIENCES,2023,125:340-348. |
APA | Ma, Guojun.,Tang, Wenxiang.,Wang, Anqi.,Zhang, Le.,Guan, Jian.,...&Chen, Yunfa.(2023).Heterojunctioned CuO/Cu 2 O catalyst for highly efficient ozone removal.JOURNAL OF ENVIRONMENTAL SCIENCES,125,340-348. |
MLA | Ma, Guojun,et al."Heterojunctioned CuO/Cu 2 O catalyst for highly efficient ozone removal".JOURNAL OF ENVIRONMENTAL SCIENCES 125(2023):340-348. |
入库方式: OAI收割
来源:过程工程研究所
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