Structure-resolved CFD simulations to guide catalyst packing of selective NO reduction
文献类型：期刊论文
| 作者 | Chen, Hao1; Shi, Yao1; Li, Zhao1; Yu, Jian2; Duan, Xuezhi1 |
| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2022-10-15 |
| 卷号 | 446页码:11 |
| 关键词 | Selective catalytic reduction Structure-resolved CFD simulation Optimization of catalyst macrostructure Catalyst packing |
| ISSN号 | 1385-8947 |
| DOI | 10.1016/j.cej.2022.136888 |
| 英文摘要 | In this work, monolith and packing structures with different particle shapes (cylinder, sphere, trilobe and Raschig ring) are compared to boost selective catalytic reduction (SCR) of NO reaction. The three-dimension structureresolved reactor model is established to evaluate the influence of mass transfer and NO reaction performance in different industrial applications. The simulation results show that monolithic catalysts shift from transition regime to reaction-controlled regime, while the cylinder-resolved catalysts shift from diffusion-controlled regime to transition regime as the reaction temperature decreases from 240 to 160 degrees C for SCR of NO. The monolithic catalyst with excellent mass transfer capacity and the catalyst with cylinder packing structure with high bulk density exhibit highest NO removal efficiency in the coking plant (-240 degrees C) and boiler system (-160 degrees C), respectively. The catalyst with Raschig ring packing structure exhibits the highest NO removal efficiency in the waste incineration plant (-200 degrees C) due to the compromise of reaction-diffusion behavior. A strategy of catalyst structures selection for SCR of NO reaction at different industrial applications based on the reaction-diffusion interaction is proposed, which could shed new light on boosting selective catalytic reduction of NO reaction. |
| WOS关键词 | SO2 OXIDATION ; HEAT-TRANSFER ; MASS-TRANSFER ; FLUE-GAS ; MONOLITH ; SCR ; GEOMETRY ; REMOVAL ; NH3-SCR ; DENO(X) |
| 资助项目 | Natural Science Foun-dation of China[22038003] ; Natural Science Foun-dation of China[21922803] ; Natural Science Foun-dation of China[22178100] ; Natural Science Foun-dation of China[21776077] ; Innovation Program of Shanghai Municipal Education Commission[21XD1421000] ; Program of Shanghai Academic/Technology Research Leader |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000807019600004 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | Natural Science Foun-dation of China ; Innovation Program of Shanghai Municipal Education Commission ; Program of Shanghai Academic/Technology Research Leader |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/53749]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Duan, Xuezhi |
| 作者单位 | 1.East China Univ Sci & Technol, State Key Lab Chem Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Hao,Shi, Yao,Li, Zhao,et al. Structure-resolved CFD simulations to guide catalyst packing of selective NO reduction[J]. CHEMICAL ENGINEERING JOURNAL,2022,446:11. |
| APA | Chen, Hao,Shi, Yao,Li, Zhao,Yu, Jian,&Duan, Xuezhi.(2022).Structure-resolved CFD simulations to guide catalyst packing of selective NO reduction.CHEMICAL ENGINEERING JOURNAL,446,11. |
| MLA | Chen, Hao,et al."Structure-resolved CFD simulations to guide catalyst packing of selective NO reduction".CHEMICAL ENGINEERING JOURNAL 446(2022):11. |
入库方式： OAI收割
来源：过程工程研究所
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