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Optimizing Lattice Strain and Electron Effect of Ultrathin Platinum Nanoshells through Core-Shell Construction toward Superior Electrocatalytic Hydrogen Evolution

文献类型：期刊论文

作者Zeng, Qing2,3; Song, Jing4,5; Cui, Penglei2; Liu, Hui1,2; Tian, Liangliang6; Chen, Dong1,2; Yang, Jun1,2,3
刊名INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
出版日期2022-06-08
卷号61期号:22页码:7529-7536
ISSN号0888-5885
DOI10.1021/acs.iecr.1c04793
英文摘要For optimizing the lattice strain and electron effect of Pt catalysts toward boosting their intrinsic electrocatalytic properties, we herein report the building of ultrathin Pt nanoshells in subnanoscale on the fine AgPd alloy cores, which are produced by alloying Pd atoms into the Ag nanoparticles through galvanic replacement reaction (GRR). Because of the smaller lattice expansion and modified electron effect of the ultrathin Pt shells in core-shell AgPd@Pt nanoparticles relative to those in core-shell Ag@Pt counterparts, the d-band center of core-shell AgPd@Pt nanoparticles locates at a lower position, favorable for weakening the adsorption of hydrogen and promoting their electrocatalysis for hydrogen evolution reaction (HER) in an acidic medium. Specifically, the core-shell AgPd@Pt nanoparticles with an appropriate Pt shell thickness not only show the lowest overpotential of 15.8 mV at 10 mA cm(-2) in comparison with 27 mV of core-shell Ag@Pt nanoparticles, and 35 mV of commercial Pt/C catalyst, but also possesses the highest mass activity (1092.6 A g(-1)) at the overpotential of 25 mV, which is 1.58 times higher than that of core-shell Ag@Pt nanoparticles (693.5 A g(-1)) and 6.74 times higher than that of commercial Pt/C (162 A g(-1)). Moreover, alloying Pd into Ag cores also endows the ultrathin Pt shells with excellent electrocatalytic durability for HER. The concept of both lattice strain and electronic engineering through a core-shell construction may provide guidance for designing other highly catalytic and cost-effective nanostructures for a myriad of electrochemical reactions.
WOS关键词OXYGEN REDUCTION ; AQUEOUS SYNTHESIS ; PT NANOPARTICLES ; OXIDATION ; CATALYSTS ; ENERGY ; NANOSTRUCTURES ; DEPENDENCE ; SURFACE ; DESIGN
资助项目National Natural Science Foundation of China[22075290] ; National Natural Science Foundation of China[21776292] ; Beijing Natural Science Foundation[Z200012] ; State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences[MPCS-2021-A-05] ; Nanjing IPE Institute of Green Manufacturing Industry[E0010725]
WOS研究方向Engineering
语种英语
WOS记录号WOS:000810028300001
出版者AMER CHEMICAL SOC
资助机构National Natural Science Foundation of China ; Beijing Natural Science Foundation ; State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences ; Nanjing IPE Institute of Green Manufacturing Industry
源URL[http://ir.ipe.ac.cn/handle/122111/53863]  
专题中国科学院过程工程研究所
通讯作者Chen, Dong; Yang, Jun
作者单位1.Nanjing IPE Inst Green Mfg Ind, Nanjing 211100, Jiangsu, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
4.Chinese Acad Sci, Inst Proc Engn, Natl Engn Res Ctr Green Recycling Strateg Met Res, Beijing 100190, Peoples R China
5.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
6.Chongqing Univ Arts & Sci, Sch Elect Informat & Elect, Chongqing 400000, Peoples R China
推荐引用方式
GB/T 7714		 Zeng, Qing,Song, Jing,Cui, Penglei,et al. Optimizing Lattice Strain and Electron Effect of Ultrathin Platinum Nanoshells through Core-Shell Construction toward Superior Electrocatalytic Hydrogen Evolution[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2022,61(22):7529-7536.
APA Zeng, Qing.,Song, Jing.,Cui, Penglei.,Liu, Hui.,Tian, Liangliang.,...&Yang, Jun.(2022).Optimizing Lattice Strain and Electron Effect of Ultrathin Platinum Nanoshells through Core-Shell Construction toward Superior Electrocatalytic Hydrogen Evolution.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,61(22),7529-7536.
MLA Zeng, Qing,et al."Optimizing Lattice Strain and Electron Effect of Ultrathin Platinum Nanoshells through Core-Shell Construction toward Superior Electrocatalytic Hydrogen Evolution".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 61.22(2022):7529-7536.

入库方式： OAI收割

来源：过程工程研究所

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