Core-shell-like Fe2O3/MgO oxygen carriers matched with fluidized bed reactor for chemical looping reforming
文献类型：期刊论文
| 作者 | Sun, Yanru1,2; Li, Jun1,2; Li, Hongzhong1,2 |
| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2022-03-01 |
| 卷号 | 431页码:12 |
| 关键词 | Oxygen carrier Fluidized bed Structure design Chemical looping dry reforming |
| ISSN号 | 1385-8947 |
| DOI | 10.1016/j.cej.2021.134173 |
| 英文摘要 | Large Fe2O3/MgO microspheres with core-shell-like structures were synthesized via hydrothermal precipitation method based on the difference solubility product constants of ferrous carbonate and magnesium carbonate. The particle morphology of the Fe2O3/MgO microspheres is dominated by polyvinylpyrrolidone (PVP), while the diameter of the Fe2O3/MgO microspheres is affected by the relative nucleation rate and growth rate. The diameter of the Fe2O3/MgO microspheres decreases with increasing PVP concentration due to the enhanced steric hindrance which inhibits the growth of crystals by hindering the collisions and aggregation between crystals. The particle diameter also decreases with increasing urea concentration, which is attributed to the enhanced nucleation rate of crystals. The reactivity of the core-shell-like Fe2O3/MgO microsphere used as oxygen carriers for chemical looping dry reforming was also investigated in a fluidized bed reactor. The core-shell-like Fe2O3/MgO microspheres show good sintering resistance and remarkable cycle stability due to the effective inhibition of iron ion diffusion and surface enrichment. |
| WOS关键词 | IRON-OXIDE ; HYDROGEN GENERATION ; COMBUSTION ; METHANE ; CATALYST ; REDUCTION ; STABILITY ; MECHANISM ; KINETICS ; AL2O3 |
| 资助项目 | National Natural Science Foundation of China[21978300] ; National Natural Science Foundation of China[21736010] ; Science Fund for Creative Research Groups of the National Natural Science Foundation of China[21921005] ; Fund of State Key Laboratory of Multiphase complex systems[MPCS-2019-A-06] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000819741800003 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | National Natural Science Foundation of China ; Science Fund for Creative Research Groups of the National Natural Science Foundation of China ; Fund of State Key Laboratory of Multiphase complex systems |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/54030]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Li, Jun |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Yanru,Li, Jun,Li, Hongzhong. Core-shell-like Fe2O3/MgO oxygen carriers matched with fluidized bed reactor for chemical looping reforming[J]. CHEMICAL ENGINEERING JOURNAL,2022,431:12. |
| APA | Sun, Yanru,Li, Jun,&Li, Hongzhong.(2022).Core-shell-like Fe2O3/MgO oxygen carriers matched with fluidized bed reactor for chemical looping reforming.CHEMICAL ENGINEERING JOURNAL,431,12. |
| MLA | Sun, Yanru,et al."Core-shell-like Fe2O3/MgO oxygen carriers matched with fluidized bed reactor for chemical looping reforming".CHEMICAL ENGINEERING JOURNAL 431(2022):12. |
入库方式： OAI收割
来源：过程工程研究所
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