Li-Deficient Materials-Decoration Restrains Oxygen Evolution Achieving Excellent Cycling Stability of Li-Rich Mn-Based Cathode
文献类型:期刊论文
作者 | Ji, Xueqian1,2; Xu, Yuxing1,3; Xia, Qing1,3; Zhou, Yuncheng1,2; Song, Jiechen1,2; Feng, Hailan1,3; Wang, Pengfei1,3; Yang, Jun1; Tan, Qiangqiang1,2 |
刊名 | ACS APPLIED MATERIALS & INTERFACES |
出版日期 | 2022-06-23 |
页码 | 11 |
ISSN号 | 1944-8244 |
关键词 | KEYWORDS lithium-ion batteries layered cathode oxygen evolution surface modi fi cation excellent cyclability |
DOI | 10.1021/acsami.2c03073 |
英文摘要 | With the increasing demand for high energy density and rapid charging performance, Li-rich materials have been the up and coming cathodes for next-generation lithium-ion batteries. However, because of oxygen evolution and structural instability, the commercialization of Li-rich materials is extremely retarded by their poor electrochemical performances. In this work, Li-deficient materials Li0.3NbO2 and (Nb0.62Li0.15)TiO3 are applied to functionalize the surface of Li1.2Mn0.54Ni0.13Co0.13O2, aiming to suppress oxygen evolution and increase structural stability in LIBs. In addition, a fast Li-ion transport channel is beneficial to enhance Li+ diffusion kinetics. The results demonstrate that the electrodes decorated with Li0.3NbO2 and (Nb0.62Li0.15)TiO3 materials exhibit more stable cycling stability after long-term cycling and outstanding rate capability. |
WOS关键词 | ENHANCED ELECTROCHEMICAL PERFORMANCE ; IN-SITU ; STORAGE PERFORMANCE ; REDOX ACTIVITY ; ANIONIC REDOX ; OXIDE ; LI1.2MN0.54NI0.13CO0.13O2 ; NANOTUBES ; ORIGIN ; RAMAN |
资助项目 | National Natural Science Foundation of China[51902310] ; Open Research Fund of State Key Laboratory of Multiphase Complex Systems[MPCS-2021-D-13] ; Joint Funds of Innovation Academy for Green Manufacture of Chinese Academy of Sciences[IAGM2020C02] ; Natural Science Foundation of Hebei Province[E2019103017] ; Natural Science Foundation of Hebei Province[E2019103018] ; Key R&D Program of Hebei Province[19214407D] |
WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000818792100001 |
资助机构 | National Natural Science Foundation of China ; Open Research Fund of State Key Laboratory of Multiphase Complex Systems ; Joint Funds of Innovation Academy for Green Manufacture of Chinese Academy of Sciences ; Natural Science Foundation of Hebei Province ; Key R&D Program of Hebei Province |
源URL | [http://ir.ipe.ac.cn/handle/122111/54087] |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Tan, Qiangqiang |
作者单位 | 1.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China 3.Hebei Technol Innovat Ctr Adv Energy Mat, Langfang 065001, Peoples R China |
推荐引用方式 GB/T 7714 | Ji, Xueqian,Xu, Yuxing,Xia, Qing,et al. Li-Deficient Materials-Decoration Restrains Oxygen Evolution Achieving Excellent Cycling Stability of Li-Rich Mn-Based Cathode[J]. ACS APPLIED MATERIALS & INTERFACES,2022:11. |
APA | Ji, Xueqian.,Xu, Yuxing.,Xia, Qing.,Zhou, Yuncheng.,Song, Jiechen.,...&Tan, Qiangqiang.(2022).Li-Deficient Materials-Decoration Restrains Oxygen Evolution Achieving Excellent Cycling Stability of Li-Rich Mn-Based Cathode.ACS APPLIED MATERIALS & INTERFACES,11. |
MLA | Ji, Xueqian,et al."Li-Deficient Materials-Decoration Restrains Oxygen Evolution Achieving Excellent Cycling Stability of Li-Rich Mn-Based Cathode".ACS APPLIED MATERIALS & INTERFACES (2022):11. |
入库方式: OAI收割
来源:过程工程研究所
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