The structure-activity relationship of aromatic compounds in advanced oxidation processes:a review
文献类型：期刊论文
| 作者 | Ren, Mingzhu1,3; Sun, Sihan1; Wu, Yiqiu1; Shi, Yanchun1,2; Wang, Zhou-jun3; Cao, Hongbin1,2; Xie, Yongbing1,2 |
| 刊名 | CHEMOSPHERE
 |
| 出版日期 | 2022-06-01 |
| 卷号 | 296页码:14 |
| 关键词 | Advanced oxidation process Aromatic compounds Reactive oxygen species Structure-activity relationship Substituent |
| ISSN号 | 0045-6535 |
| DOI | 10.1016/j.chemosphere.2022.134071 |
| 英文摘要 | Advanced oxidation processes (AOPs) are widely used as efficient technologies to treat highly toxic and harmful substances in wastewater. Taking the most representative aromatic compounds (monosubstituted benzenes, substituted phenols and heterocyclic compounds) as examples, this paper firstly introduces their structures and the structural descriptors studied in AOPs before, and the influence of structural differences in AOPs with different reactive oxygen species (ROS) on the degradation rate was discussed in detail. The structure-activity relationship of pollutants has been previously analyzed through quantitative structure-activity relationship (QSAR) model, in which ROS is a very important influencing factor. When electrophilic oxidative species attacks pollutants, aromatic compounds with electron donating groups are more favorable for degradation than aromatic compounds with electron donating groups. While nucleophilic oxidative species comes to the opposite conclusion. The choice of advanced oxidation processes, the synergistic effect of various active oxygen species and the used catalysts will also change the degradation mechanism. This makes the structure-dependent activity relationship uncertain, and different conclusions are obtained under the influence of various experimental factors. |
| WOS关键词 | P-SUBSTITUTED PHENOLS ; ACTIVITY-RELATIONSHIP QSAR ; REACTION-RATE CONSTANTS ; WET AIR OXIDATION ; PHOTOCATALYTIC DEGRADATION ; ELECTROCHEMICAL OXIDATION ; ORGANIC-COMPOUNDS ; SINGLET OXYGEN ; BENZENE-DERIVATIVES ; AQUEOUS SUSPENSIONS |
| 资助项目 | State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization[2021P4FZG04A] |
| WOS研究方向 | Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:000819945200008 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/54142]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Xie, Yongbing |
| 作者单位 | 1.Chinese Acad Sci, Beijing Engn Res Ctr Proc Pollut Control, Inst Proc Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Natl Basic Publ Sci Data Ctr, Beijing 100190, Peoples R China 3.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing Key Lab Energy Environm Catalysis, Beijing 100029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ren, Mingzhu,Sun, Sihan,Wu, Yiqiu,et al. The structure-activity relationship of aromatic compounds in advanced oxidation processes:a review[J]. CHEMOSPHERE,2022,296:14. |
| APA | Ren, Mingzhu.,Sun, Sihan.,Wu, Yiqiu.,Shi, Yanchun.,Wang, Zhou-jun.,...&Xie, Yongbing.(2022).The structure-activity relationship of aromatic compounds in advanced oxidation processes:a review.CHEMOSPHERE,296,14. |
| MLA | Ren, Mingzhu,et al."The structure-activity relationship of aromatic compounds in advanced oxidation processes:a review".CHEMOSPHERE 296(2022):14. |
入库方式： OAI收割
来源：过程工程研究所
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