Base-free synthesis of bio-derived 2,5-furandicarboxylic acid using SBA-15 supported heteropoly acids in ionic liquids
文献类型：期刊论文
| 作者 | Chen, Ruru6; Zhao, Qiu1,6; Yan, Dongxia2,6; Xin, Jiayu3,4,5,6; Lu, Xingmei3,4,5,6 |
| 刊名 | CHEMISTRYSELECT
 |
| 出版日期 | 2022-07-07 |
| 卷号 | 7期号:25页码:7 |
| ISSN号 | 2365-6549 |
| 关键词 | 2 5-Furandicarboxylic Acid Heteropoly Acids Green chemistry SBA-15 Ionic Liquids |
| DOI | 10.1002/slct.202200529 |
| 英文摘要 | 2,5-Furandicarboxylic acid (FDCA) is a green and renewable substitute to terephthalic acid (TPA), the fundamental monomer of polyethylene terephthalate (PET) plastic. This work investigated novel supported Keggin phosphormolybdic acids (HPMs) for the synthesis of FDCA from 5-hydroxymethylfurfural (HMF) in imidazole ionic liquids. Among four supporters, Al2O3, SiO2, ZSM-5 and SBA-15, SBA-15 exhibited highest stability and specific surface area 507 m(2)/g. FDCA yield achieved 76 % by using HPM/SBA-15, and maintained 60 % after 5 runs. Particularly, [Bmim]Cl ionic liquid was stable both in thermal and chemical properties by confirmation of FTIR and NMR. HPM/SBA-15 was also employed in different monosaccharides to FDCA, and led to acceptable yields. A moderate FDCA yield of 34 % from glucose was obtained, revealing a great potential of one-pot synthesis of FDCA from renewable and accessible carbohydrates. |
| WOS关键词 | AEROBIC OXIDATION ; CATALYTIC PERFORMANCE ; SELECTIVE OXIDATION ; FREE CONVERSION ; AQUEOUS-PHASE ; NANOPARTICLES ; REDUCTION ; FRUCTOSE ; FE |
| 资助项目 | National Key R&D Program of China[2021YFC2101800] ; National Key R&D Program of China[2021YFE0190800] ; National Natural Science Foundation of China[21878314] ; National Natural Science Foundation of China[22178343] ; National Natural Science Foundation of China[22178358] ; Hebei Natural Science Foundation[B2021103003] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000819989500001 |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Hebei Natural Science Foundation |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/54182]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Xin, Jiayu |
| 作者单位 | 1.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Henan, Peoples R China 2.Langfang Technol Ctr Green Ind, Langfang 065006, Hebei, Peoples R China 3.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China 4.Univ Chinese Acad Sci, Sino Danish Coll, Beijing 100049, Peoples R China 5.Chinese Acad Sci, Inst Proc Engn, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China 6.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, CAS Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Ruru,Zhao, Qiu,Yan, Dongxia,et al. Base-free synthesis of bio-derived 2,5-furandicarboxylic acid using SBA-15 supported heteropoly acids in ionic liquids[J]. CHEMISTRYSELECT,2022,7(25):7. |
| APA | Chen, Ruru,Zhao, Qiu,Yan, Dongxia,Xin, Jiayu,&Lu, Xingmei.(2022).Base-free synthesis of bio-derived 2,5-furandicarboxylic acid using SBA-15 supported heteropoly acids in ionic liquids.CHEMISTRYSELECT,7(25),7. |
| MLA | Chen, Ruru,et al."Base-free synthesis of bio-derived 2,5-furandicarboxylic acid using SBA-15 supported heteropoly acids in ionic liquids".CHEMISTRYSELECT 7.25(2022):7. |
入库方式： OAI收割
来源：过程工程研究所
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