Promoting effect of Fe/La loading on gamma-Al2O3 catalyst for hydrolysis of carbonyl sulfur
文献类型：期刊论文
| 作者 | Gao, Panting1,2; Li, Yuran2; Lin, Yuting2; Chang, Liping1; Zhu, Tingyu2 |
| 刊名 | ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
 |
| 出版日期 | 2022-07-01 |
| 页码 | 14 |
| ISSN号 | 0944-1344 |
| 关键词 | Catalytic hydrolysis of COS Aluminum oxide-based catalyst H2S oxidation Transition metal or rare earth metal modification Blast furnace gas |
| DOI | 10.1007/s11356-022-20928-1 |
| 英文摘要 | Catalytic hydrolysis of carbonyl sulfur (COS) from blast furnace gas is one of the keys to achieving ultra-low emission in the iron-steel industry. To improve the COS hydrolysis activity on gamma-Al2O3 catalyst at low temperature, catalysts with Fe or La as the active component were prepared by the impregnation method, the physical and chemical properties of the catalyst were characterized by ICP, XRF, XRD, BET, and TPD. The hydrolysis activity of COS and sulfur resistance ability on various catalysts were investigated in a fixed bed reactor combined with gas chromatography. The results show that the addition of Fe or La improves the COS hydrolysis activity due to the increase in alkaline sites on the catalyst surface. The roles of various alkaline sites on catalysts have been recognized. The weak alkaline center is the reaction site of COS hydrolysis, the middle and strong alkaline centers are the adsorption and oxidation sites of H2S. The Fe/Al2O3 catalyst has higher hydrolytic activity and oxidative capacity for H2S removal due to forming more sulfate species on Fe. The La/Al2O3 catalyst has higher hydrolysis efficiency in that H2S rapidly desorbs from the catalyst surface to the gas phase, and then, the activity of reaction sites is recovered. This provides an idea for the preparation of sulfur-resistant catalysts. |
| WOS关键词 | ACTIVATED CARBONS ; SIMULTANEOUS REMOVAL ; H2S REMOVAL ; SULFIDE ; COS ; GAS ; CS2 ; PERFORMANCE ; ADSORPTION ; DISULFIDE |
| 资助项目 | Key Research and Development Program of Hebei Province[21373702D] ; Key Science and Technology Program of HBIS Group Co., Ltd[HG2021117] |
| WOS研究方向 | Environmental Sciences & Ecology |
| 语种 | 英语 |
| 出版者 | SPRINGER HEIDELBERG |
| WOS记录号 | WOS:000819696800011 |
| 资助机构 | Key Research and Development Program of Hebei Province ; Key Science and Technology Program of HBIS Group Co., Ltd |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/54200]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Li, Yuran |
| 作者单位 | 1.Taiyuan Univ Technol, State Key Lab Clean & Efficient Coal Utilizat, Taiyuan 030024, Peoples R China 2.Chinese Acad Sci, Innovat Acad Green Manufacture, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Panting,Li, Yuran,Lin, Yuting,et al. Promoting effect of Fe/La loading on gamma-Al2O3 catalyst for hydrolysis of carbonyl sulfur[J]. ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,2022:14. |
| APA | Gao, Panting,Li, Yuran,Lin, Yuting,Chang, Liping,&Zhu, Tingyu.(2022).Promoting effect of Fe/La loading on gamma-Al2O3 catalyst for hydrolysis of carbonyl sulfur.ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,14. |
| MLA | Gao, Panting,et al."Promoting effect of Fe/La loading on gamma-Al2O3 catalyst for hydrolysis of carbonyl sulfur".ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2022):14. |
入库方式： OAI收割
来源：过程工程研究所
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