A novel and versatile precursor for the synthesis of highly preorganized tetradentate ligands based on phenanthroline and their binding properties towards lanthanides(III) ions
文献类型：期刊论文
| 作者 | Duan, Li1; Fan, Jinlong1; Tian, Deshun2,3; Yan, Qiang4; Zhang, Xiangbo1; Li, Pengcheng2; Xu, Chao4; Wang, Li3 |
| 刊名 | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
 |
| 出版日期 | 2022-08-20 |
| 卷号 | 647页码:10 |
| 关键词 | Preorganized ligands Phenanthroline Lanthanides separation Binding thermodynamics |
| ISSN号 | 0927-7757 |
| DOI | 10.1016/j.colsurfa.2022.129089 |
| 英文摘要 | Rare earth elements (REEs) are vitally important for both high-tech industry and homeland security. Current industrial production and purification of REEs rely mostly on solvent extraction, for which, the overall extraction efficiency is largely determined by the organic ligands used as extractants. Ligands based on 1,10-phenantroline-2,9-diamides (PhenDA) are promising candidates and have been intensively investigated for both lanthanides (Lns) and/or lanthanides/actinides (Lns/Ans) separations. The synthetic drawback for current PhenDA derivatives lies in the equivalent usage of acyl chloride for the key precursors, thus limiting functional group tolerance and large-scale production of the extractants. Herein, we have demonstrated a new synthetic approach for mild reaction condition, high-yield synthesis of various types of PhenDA derivatives ranging from alkyl, aromatic to amino acid substituents. The synthetic procedures are relatively green for the absence of corrosive, volatile reagents and easy of product purification. The in-group Lns discrimination of one ligand is investigated in detail to demonstrate the separation potential. Considering the broad functional group tolerance of the current method and ease of large-scale production, we believe the methodology will broaden the ligands scope based on PhenDA and inspire new functionalities of Lns complexes. |
| WOS关键词 | RARE-EARTH-ELEMENTS ; TRIVALENT LANTHANIDES ; MINOR ACTINIDES ; AMIDE OXYGEN ; METAL-IONS ; EXTRACTION ; SELECTIVITY ; SEPARATION ; DONOR ; COMPLEXATION |
| 资助项目 | Start-up Program of Institute of Process Engineering, IPE Talent Program-Category B[E0297902] ; State Key Laboratory of Biochemical Engineering[E1297901] ; National Natural Science Foundation of China[21822606] ; National Natural Science Foundation of China[21790372] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000830344600002 |
| 出版者 | ELSEVIER |
| 资助机构 | Start-up Program of Institute of Process Engineering, IPE Talent Program-Category B ; State Key Laboratory of Biochemical Engineering ; National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/54267]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Duan, Li; Xu, Chao; Wang, Li |
| 作者单位 | 1.Northwest Inst Nucl Technol, Xian 710024, Shaanxi, Peoples R China 2.Wuhan Inst Technol, Inst Mat Optoelect & New Energy, Hubei Key Lab Plasma Chem & Adv Mat, Sch Mat Sci & Engn, Wuhan 430205, Peoples R China 3.Chinese Acad Sci, State Key Lab Biochem Engn, Inst Proc Engn, Beijing 100190, Peoples R China 4.Tsinghua Univ, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China |
| 推荐引用方式 GB/T 7714 | Duan, Li,Fan, Jinlong,Tian, Deshun,et al. A novel and versatile precursor for the synthesis of highly preorganized tetradentate ligands based on phenanthroline and their binding properties towards lanthanides(III) ions[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2022,647:10. |
| APA | Duan, Li.,Fan, Jinlong.,Tian, Deshun.,Yan, Qiang.,Zhang, Xiangbo.,...&Wang, Li.(2022).A novel and versatile precursor for the synthesis of highly preorganized tetradentate ligands based on phenanthroline and their binding properties towards lanthanides(III) ions.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,647,10. |
| MLA | Duan, Li,et al."A novel and versatile precursor for the synthesis of highly preorganized tetradentate ligands based on phenanthroline and their binding properties towards lanthanides(III) ions".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 647(2022):10. |
入库方式： OAI收割
来源：过程工程研究所
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