Robust Multiscale Electron/Ion Transport and Enhanced Structural Stability in SiOx Semi-Solid Anolytes Enabled by Trifunctional Artificial Interfaces for High-Performance Li-Ion Slurry Flow Batteries
文献类型：期刊论文
| 作者 | Pan, Shanshan1,2; Yang, Lipeng1; Su, Peipei1,3; Zhang, Haitao1,3; Zhang, Suojiang1,3 |
| 刊名 | SMALL
 |
| 出版日期 | 2022-07-24 |
| 页码 | 13 |
| 关键词 | Li-ion slurry flow batteries multiscale electron ion transport SiO (x) semi-solid anolytes structural integrity trifunctional interfaces |
| ISSN号 | 1613-6810 |
| DOI | 10.1002/smll.202202139 |
| 英文摘要 | SiOx suspension is regarded as an attractive anolyte for high-energy-density Li-ion slurry flow batteries. However, the poor electronic conductivity and non-negligible volume variation of SiOx greatly hinder its practical applications. Herein, these issues are successfully addressed by rationally designing a trifunctional interface with mixed electron/ion and hard/soft modulated properties on SiOx surface via H-bonding interactions. The interface comprises a lithiated polymer layer (LiPN) interfused with functionalized single-walled carbon nanotubes. Carbon nanotubes work as electrical tentacles to enhance the multiscale electron conduction. The LiPN layer with transferable Li-ions facilitates ion transport. In addition, the LiPN layer employs lithiated rigid polyacrylic acid as a framework to provide mechanical support and soft nafion as a buffer to accommodate volume change, which maintains the structural integrity of SiOx. Hence, SiOx@LiPN/S anolytes exhibit significantly improved rate and cycle performances. Specially, the interface enables the anolytes to load more active particles (30 wt%) or less conductive additives (0.4 wt%). The semi-solid pouch cells based on high-active-content anolytes with stable cyclability are first demonstrated and the flow cell using low-conductive-content anolytes displays a high volumetric capacity of 207 Ah L-1. This strategy paves a novel approach for optimizing semi-solid electrodes for high-performance Li-ion slurry flow batteries. |
| WOS关键词 | ENERGY-STORAGE ; LITHIUM ; ANODE ; INTERPHASE ; ELECTRODES ; COMPOSITE ; CARBON ; BINDER ; LAYER ; MASS |
| 资助项目 | National Key Research and Development Program of China[2019YFA0705601] ; National Natural Science Foundation of China[21878308] ; Major Program of National Natural Science Foundation of China[21890762] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000830320600001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Key Research and Development Program of China ; National Natural Science Foundation of China ; Major Program of National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/54300]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Zhang, Haitao; Zhang, Suojiang |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Future Technol, Beijing 100049, Peoples R China 3.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pan, Shanshan,Yang, Lipeng,Su, Peipei,et al. Robust Multiscale Electron/Ion Transport and Enhanced Structural Stability in SiOx Semi-Solid Anolytes Enabled by Trifunctional Artificial Interfaces for High-Performance Li-Ion Slurry Flow Batteries[J]. SMALL,2022:13. |
| APA | Pan, Shanshan,Yang, Lipeng,Su, Peipei,Zhang, Haitao,&Zhang, Suojiang.(2022).Robust Multiscale Electron/Ion Transport and Enhanced Structural Stability in SiOx Semi-Solid Anolytes Enabled by Trifunctional Artificial Interfaces for High-Performance Li-Ion Slurry Flow Batteries.SMALL,13. |
| MLA | Pan, Shanshan,et al."Robust Multiscale Electron/Ion Transport and Enhanced Structural Stability in SiOx Semi-Solid Anolytes Enabled by Trifunctional Artificial Interfaces for High-Performance Li-Ion Slurry Flow Batteries".SMALL (2022):13. |
入库方式： OAI收割
来源：过程工程研究所
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