The catalytic effect of inner minerals on the combustion of oil shale char: Characteristics and mechanism
文献类型：期刊论文
| 作者 | Yan, Yulin1,2,3; Gao, He3; Sui, Yi3; Hu, Zhiyong5; Han, Zhennan3; Xu, Guangwen3,4 |
| 刊名 | FUEL PROCESSING TECHNOLOGY
 |
| 出版日期 | 2022-11-01 |
| 卷号 | 236页码:15 |
| 关键词 | Micro fluidized bed Oil shale Carbon structure Char combustion Catalysis Minerals |
| ISSN号 | 0378-3820 |
| DOI | 10.1016/j.fuproc.2022.107426 |
| 英文摘要 | To determine the effects of minerals inside char particles and bed materials, the process and mechanism of char combustion in a fluidized bed were studied using a Micro Fluidized Bed Reactor Analyzer. A demineralization procedure using HCl and HF was employed to remove the minerals from pyrolyzed char samples. Raman spectroscopy was used to study the carbon structure of the remaining solid char after demineralization at 500 degrees C, 600 degrees C, 700 degrees C and 800 degrees C. From the regular changes in band area ratio and full width at half maximum, it can be concluded that as pyrolysis temperature increases, the carbon structure becomes highly ordered, the plane lattice size gradually increases, and the reaction activity decreases from 0.245 s-1 to 0.138 s- 1.Furthermore, minerals both within the char particle and in the external bed had marked catalytic activity on char combustion, and their combined catalysis was most notable. CaO and Fe2O3 were the dominant active minerals components contributing to catalytic combustion of char in this study. The catalytic action of CaO was stronger than that of Fe2O3. The activation energy of char combustion ranged from 57.70 kJ/mol to 91.53 kJ/mol, and it significantly decreased in the presence of the bed materials. |
| WOS关键词 | MICRO FLUIDIZED-BED ; SOLID HEAT CARRIER ; RAMAN-SPECTROSCOPIC CHARACTERIZATION ; COAL CHAR ; MOVING-BED ; MICROSTRUCTURAL CHANGES ; CARBONACEOUS MATERIALS ; TG-FTIR ; PYROLYSIS ; GASIFICATION |
| 资助项目 | National Natural Science Foundation of China[U1903130] ; Ministry of Science and Technology of the People?s Republic of China[2020YFC1909305] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000835230300001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; Ministry of Science and Technology of the People?s Republic of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/54355]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Han, Zhennan; Xu, Guangwen |
| 作者单位 | 1.Shale Oil Plant Fushun Min Grp Co Ltd, Fushun 113115, Liaoning, Peoples R China 2.Univ Sci & Technol Liaoning, Sch Chem Engn, Anshan 114051, Liaoning, Peoples R China 3.Shenyang Univ Chem Technol, Inst Ind Chem & Energy Technol, Lab Resources Chem & Mat, Minist Educ, Shenyang 110142, Liaoning, Peoples R China 4.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 5.Liaoning Petrochem Univ, Coll Petr & Nat Gas Engn, Fushun 113001, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yan, Yulin,Gao, He,Sui, Yi,et al. The catalytic effect of inner minerals on the combustion of oil shale char: Characteristics and mechanism[J]. FUEL PROCESSING TECHNOLOGY,2022,236:15. |
| APA | Yan, Yulin,Gao, He,Sui, Yi,Hu, Zhiyong,Han, Zhennan,&Xu, Guangwen.(2022).The catalytic effect of inner minerals on the combustion of oil shale char: Characteristics and mechanism.FUEL PROCESSING TECHNOLOGY,236,15. |
| MLA | Yan, Yulin,et al."The catalytic effect of inner minerals on the combustion of oil shale char: Characteristics and mechanism".FUEL PROCESSING TECHNOLOGY 236(2022):15. |
入库方式： OAI收割
来源：过程工程研究所
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