Improved Reversible Zinc Storage Achieved in a Constitutionally Crystalline-Stable Mn(VO3)(2) Nanobelts Cathode
文献类型:期刊论文
作者 | Ke, Jiaqi2; Zhang, Yufei1,2; Zhang, Yibo3; Ye, Minghui2; Zhang, Zicheng2; Tang, Yongchao2; Liu, Xiaoqing2; Li, Cheng Chao1,2 |
刊名 | CHEMISTRY-A EUROPEAN JOURNAL |
出版日期 | 2022-08-03 |
页码 | 11 |
ISSN号 | 0947-6539 |
关键词 | cathode energy storage device manganese vanadate tunnel structure zinc ion batteries |
DOI | 10.1002/chem.202201687 |
英文摘要 | Rechargeable zinc-ion batteries (ZIBs) are potential for grid-scale applications owing to their safety, low price, and available sources. The development of ZIBs cathode with high specific capacity, wide operating voltage window and stable cyclability is urgently needed in next-generation commercial batteries. Herein, we report a structurally crystalline-stable Mn(VO3)(2) nanobelts cathode for ZIBs prepared via a facile hydrothermal method. The as-synthesized Mn(VO3)(2) exhibited high specific capacity of 350 mAh g(-1) at 0.1 A g(-1), and maintained a capacity retention of 92 % after 10,000 cycles at 2 A g(-1). It also showed good rate performance and obtained a reversible capacity of up to 200 mAh g(-1) after 600 cycles at 0.2 A g(-1) under -20 degrees C. The electrochemical tests suggest that Mn(VO3)(2) nanobelts impart fast Zn2+ ions migration, and the introduction of manganese atoms help make the structures more indestructible, leading to a good rate performance and prolonged cycle lifespan. |
WOS关键词 | ION BATTERY ; INTERCALATION ; NANOSHEETS ; VANADATES ; MECHANISM |
资助项目 | National Natural Science Foundation of China[51771058] ; National Natural Science Foundation of China[52101243] ; Pearl River Talent Program of Guangdong Province[2017GC010030] ; Guangdong Basic and Applied Basic Research Foundation[2020A1515010886] ; Guangdong Basic and Applied Basic Research Foundation[2021A0505030067] ; Guangdong Provincial Key Laboratory of Plant Resources Biorefinery[2021GDKLPRB12] |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | WILEY-V C H VERLAG GMBH |
WOS记录号 | WOS:000835321400001 |
资助机构 | National Natural Science Foundation of China ; Pearl River Talent Program of Guangdong Province ; Guangdong Basic and Applied Basic Research Foundation ; Guangdong Provincial Key Laboratory of Plant Resources Biorefinery |
源URL | [http://ir.ipe.ac.cn/handle/122111/54415] |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Li, Cheng Chao |
作者单位 | 1.Guangdong Prov Key Lab Plant Resources Biorefiner, Guangzhou 510006, Peoples R China 2.Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Ke, Jiaqi,Zhang, Yufei,Zhang, Yibo,et al. Improved Reversible Zinc Storage Achieved in a Constitutionally Crystalline-Stable Mn(VO3)(2) Nanobelts Cathode[J]. CHEMISTRY-A EUROPEAN JOURNAL,2022:11. |
APA | Ke, Jiaqi.,Zhang, Yufei.,Zhang, Yibo.,Ye, Minghui.,Zhang, Zicheng.,...&Li, Cheng Chao.(2022).Improved Reversible Zinc Storage Achieved in a Constitutionally Crystalline-Stable Mn(VO3)(2) Nanobelts Cathode.CHEMISTRY-A EUROPEAN JOURNAL,11. |
MLA | Ke, Jiaqi,et al."Improved Reversible Zinc Storage Achieved in a Constitutionally Crystalline-Stable Mn(VO3)(2) Nanobelts Cathode".CHEMISTRY-A EUROPEAN JOURNAL (2022):11. |
入库方式: OAI收割
来源:过程工程研究所
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