Tunable d-Band Centers of Ni5P4 Ultra-Thin Nanosheets for Highly-Efficient Hydrogen Evolution Reaction
文献类型：期刊论文
| 作者 | Miao, Chengcheng2; Zang, Yanmei2; Wang, Hang3; Zhuang, Xinming2; Han, Ning3; Yin, Yanxue2; Ma, Yandong2; Chen, Ming2; Dai, Ying2; Yip, SenPo1 |
| 刊名 | ADVANCED MATERIALS INTERFACES
 |
| 出版日期 | 2022-08-01 |
| 卷号 | 9期号:22页码:9 |
| ISSN号 | 2196-7350 |
| 关键词 | d-band center doping hydrogen evolution reaction Ni P-5 (4) ultra-thin nanosheets |
| DOI | 10.1002/admi.202200739 |
| 英文摘要 | Although the recent advance of ultra-thin 2D nanosheets for hydrogen evolution reaction (HER) is remarkable, there are still substantial challenges to reliably control their physioelectric and electrochemical properties to employ as highly-efficient electrocatalysts. Herein, based on complementary theoretical and experimental studies, the d-band center position of ultra-thin 2D Ni5P4 nanosheets can be manipulated by simple heteroatom doping. Interestingly, the Fe-doped nanosheets yield the lowest d-band center position, but they do not display the optimal Gibbs free energy of adsorbed H atoms due to the imbalance of adsorption and desorption of adsorbed H atoms. With the proper Co doping (i.e., 20%), the nanosheets exhibit the best electrocatalytic performance along with an excellent stability. The overpotential is only 100.5 mV at 10 mA cm(-2) with a Tafel slope of 65.8 mV dec(-1), which is superior than those of Fe-doped, Cu-doped, and pristine Ni5P4 nanosheets. Ultraviolet photoelectron and X-ray photoelectron spectroscopy further verify the downshift of d-band centers of nanosheets by optimal doping, illustrating that Ni with the lower binding energy mainly dominates the active sites. All these results provide a valuable design scheme of dopants to control the d-band center position of nanosheets for next-generation highly-efficient HER electrocatalysts. |
| WOS关键词 | BIFUNCTIONAL ELECTROCATALYST ; NI FOAM ; CONSTRUCTION ; SURFACE ; ARRAYS ; SITES ; RANGE ; FILMS ; CO2P |
| 资助项目 | National Natural Science Foundation of China[61904096] ; Taishan Scholars Program of Shandong Province[tsqn201812006] ; Shandong University Multidisciplinary Research and Innovation Team of Young Scholars[2020QNQT015] ; Shandong University ; Environment and Conservation Fund of Hong Kong SAR, China[ECF 2020-13] |
| WOS研究方向 | Chemistry ; Materials Science |
| 语种 | 英语 |
| 出版者 | WILEY |
| WOS记录号 | WOS:000835528000027 |
| 资助机构 | National Natural Science Foundation of China ; Taishan Scholars Program of Shandong Province ; Shandong University Multidisciplinary Research and Innovation Team of Young Scholars ; Shandong University ; Environment and Conservation Fund of Hong Kong SAR, China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/54424]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Ma, Yandong; Ho, Johnny C.; Yang, Zai-xing |
| 作者单位 | 1.Kyushu Univ, Inst Mat Chem & Engn, Fukuoka 8168580, Japan 2.Shandong Univ, Sch Microelect, State Key Lab Crystal Mat, Sch Phys, Jinan 250100, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 4.City Univ Hong Kong, Dept Mat Sci & Engn, Hong Kong 999077, Peoples R China |
| 推荐引用方式 GB/T 7714 | Miao, Chengcheng,Zang, Yanmei,Wang, Hang,et al. Tunable d-Band Centers of Ni5P4 Ultra-Thin Nanosheets for Highly-Efficient Hydrogen Evolution Reaction[J]. ADVANCED MATERIALS INTERFACES,2022,9(22):9. |
| APA | Miao, Chengcheng.,Zang, Yanmei.,Wang, Hang.,Zhuang, Xinming.,Han, Ning.,...&Yang, Zai-xing.(2022).Tunable d-Band Centers of Ni5P4 Ultra-Thin Nanosheets for Highly-Efficient Hydrogen Evolution Reaction.ADVANCED MATERIALS INTERFACES,9(22),9. |
| MLA | Miao, Chengcheng,et al."Tunable d-Band Centers of Ni5P4 Ultra-Thin Nanosheets for Highly-Efficient Hydrogen Evolution Reaction".ADVANCED MATERIALS INTERFACES 9.22(2022):9. |
入库方式： OAI收割
来源：过程工程研究所
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