Separation of anthracene and carbazole from crude anthracene via imidazolium-based ionic liquids
文献类型：期刊论文
| 作者 | Zhao, Di1; Xiong, Yao2; Wang, Yonggang1; Lu, Beibei1; Zhang, Haiyong1 |
| 刊名 | FUEL
 |
| 出版日期 | 2023 |
| 卷号 | 331页码:10 |
| 关键词 | Anthracene Carbazole, Ionic liquids Crude anthracene Separation |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2022.125704 |
| 英文摘要 | Anthracene and carbazole, the main components of crude anthracene, have high added value in chemical in-dustry. In this study, two imidazolium-based ILs, [PM2IM][TFAc] (ILa) and [PM2IM][Ac] (ILb), were synthesized to separate anthracene and carbazole. The effective separation of anthracene and carbazole was achieved by hydrogen bonding between carbazole and imidazolium-based ILs. The results of density functional theory simulation and 1H NMR verification showed that the hydrogen bond interaction between carbazole and ILs was via C=O...H-N, and the hydrogen bond strength between ILb and carbazole was stronger than that of ILa. Based on the process for the separation of anthracene and carbazole from crude anthracene by imidazolium-based ILs, the purity of refining anthracene reached 94.89% and that of crude carbazole reached 81.60%. In addition, this process test realized recovery and recycling of ILs. |
| WOS关键词 | COAL-TAR ; EXTRACTIVE DENITROGENATION ; COSMO-RS ; OIL ; PHENANTHRENE ; IMPURITIES ; SOLUBILITY ; MECHANISM ; MODEL |
| 资助项目 | National Key Research and Development Program of China[2016YFB0600305] ; National Natural Science Foundation of China[21506251] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000859016900004 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Key Research and Development Program of China ; National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/54688]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Wang, Yonggang |
| 作者单位 | 1.China Univ Min & Technol Beijing, Sch Chem & Environm Engn, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Res Ctr Proc Pollut Control, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Di,Xiong, Yao,Wang, Yonggang,et al. Separation of anthracene and carbazole from crude anthracene via imidazolium-based ionic liquids[J]. FUEL,2023,331:10. |
| APA | Zhao, Di,Xiong, Yao,Wang, Yonggang,Lu, Beibei,&Zhang, Haiyong.(2023).Separation of anthracene and carbazole from crude anthracene via imidazolium-based ionic liquids.FUEL,331,10. |
| MLA | Zhao, Di,et al."Separation of anthracene and carbazole from crude anthracene via imidazolium-based ionic liquids".FUEL 331(2023):10. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。