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Novel Technology for the Removal of Fe and Al from Spent Li-Ion Battery Leaching Solutions by a Precipitation-Complexation Process

文献类型：期刊论文

作者Liu, Wenke1,2; Qin, Qingwei1; Zhang, Hailin2; Chen, Xing2; Luo, Ling2; Li, Guangqiang1; Zheng, Shili2; Li, Ping1,2,3
刊名ACS SUSTAINABLE CHEMISTRY & ENGINEERING
出版日期2022-09-21
页码8
关键词spent lithium-ion battery leaching solutions precipitation-complexation Fe(III) and Al(III) removal low pH phytic acid utilization
ISSN号2168-0485
DOI10.1021/acssuschemeng.2c03743
英文摘要The conventional neutralization method for removing impurities Fe(III) and Al(III) from spent Li-ion battery (LIB) leaching solutions has encountered problems of low impurity removal efficiency or high loss of valuable metals. In this study, highly selective and effective separation of Fe(III) and Al(III) from spent LIB leaching solutions was achieved by the precipitation-complexation technology. It was found that almost all Fe(III) together with most of the Al(III) could be removed by preferential precipitation using NaHCO3 neutralization under an equilibrium pH of 3.3 at 95 degrees C. Phytic acid, as a selectively complexing agent, was then introduced to completely remove the residual Al(III) from Fe-removed solutions with an Al/PA molar ratio of 3:1 at 60 degrees C. As a result, more than 99.5% Fe(III) and 97.08% Al(III) could be removed from the actual solutions, with a total loss of Ni, Co, Mn, and Li of only 1.1%. Furthermore, the obtained Al-phytates could be decomposed to form Al(PO3)(3) products at 1000 degrees C. The whole process not only realized the efficient removal of Al(III) and Fe(III) at low pH with minimal loss of Ni, Co, Mn, and Li but also reduced the emission of wastes and utilized the Al resources.
WOS关键词HYDROMETALLURGICAL PROCESS ; VALUABLE METALS ; PHYTIC ACID ; LITHIUM ; RECOVERY ; SEPARATION ; COBALT ; NI ; CO
资助项目National Natural Science Foundation of China[51974285] ; Key Research Program of the Chinese Academy of Sciences[ZDRW-CN-2021-3]
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Engineering
语种英语
WOS记录号WOS:000860551900001
出版者AMER CHEMICAL SOC
资助机构National Natural Science Foundation of China ; Key Research Program of the Chinese Academy of Sciences
源URL[http://ir.ipe.ac.cn/handle/122111/54887]  
专题中国科学院过程工程研究所
通讯作者Li, Ping
作者单位1.Wuhan Univ Sci & Technol, State Key Lab Refractories & Met, State Environm Protect Key Lab Mineral Met Resour, Wuhan 430081, Hubei, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
3.Ganjiang Innovat Acad, Chinese Acad Sci, Jiangxi Prov Key Lab Cleaner Prod Rare Earths, Ganzhou 341100, Jiangxi, Peoples R China
推荐引用方式
GB/T 7714		 Liu, Wenke,Qin, Qingwei,Zhang, Hailin,et al. Novel Technology for the Removal of Fe and Al from Spent Li-Ion Battery Leaching Solutions by a Precipitation-Complexation Process[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2022:8.
APA Liu, Wenke.,Qin, Qingwei.,Zhang, Hailin.,Chen, Xing.,Luo, Ling.,...&Li, Ping.(2022).Novel Technology for the Removal of Fe and Al from Spent Li-Ion Battery Leaching Solutions by a Precipitation-Complexation Process.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,8.
MLA Liu, Wenke,et al."Novel Technology for the Removal of Fe and Al from Spent Li-Ion Battery Leaching Solutions by a Precipitation-Complexation Process".ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022):8.

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来源：过程工程研究所

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