Template-Assisted Synthesis of Porous Manganese Dioxide Hollow Rods as Supercapacitor Electrode Material
文献类型:期刊论文
作者 | Jiang, Qinglin1; Xian, Xiaobin1; Xiao, Wei1; Zhang, Yanhua1; Deng, Ying1; Hu, Rong1; Tian, Liangliang1; Wang, Yi2; Qu, Jingkui2 |
刊名 | JOURNAL OF ELECTRONIC MATERIALS
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出版日期 | 2022-10-11 |
页码 | 11 |
关键词 | Template synthesis hollow rods MoO3 MnO2 supercapacitor |
ISSN号 | 0361-5235 |
DOI | 10.1007/s11664-022-10005-1 |
英文摘要 | We propose a facile template strategy for fabrication of porous delta manganese dioxide (delta-MnO2) hollow rods under mild conditions. First, highly dispersible molybdenum oxide (MoO3) rods were hydrothermally prepared. Next, MoO3/carbon (MoO3/C) composite rods were further synthesized by wrapping a MoO3 substrate with a polypyrrole thin layer through the oxidative polymerization of pyrrole, followed by annealing in an inert atmosphere. Finally, porous delta-MnO2 hollow rods were produced by redox reaction between the carbon component of MoO3/C and potassium permanganate (KMnO4), followed by total dissolution of MoO3 template. Such developed delta-MnO2 hollow rods were systematically characterized and found to show impressive electrochemical properties with the maximum specific capacitance of 171.3 F g(-1), satisfactory rate performance and exceptional cycle stability with capacitance retention as high as 90.5% even after repetitively charging/discharging for over 10,000 cycles. The remarkable supercapacitive behavior of porous delta-MnO2 hollow rods surpass those of many MnO2-based electrode materials, thus featuring the potential for development of advanced energy storage devices. |
WOS关键词 | ENERGY-STORAGE ; MNO2 ; NANOMATERIALS ; NANOSPHERES ; DELTA-MNO2 ; CAPACITORS ; NANOSHEETS ; CATALYSTS ; SPHERES ; DESIGN |
资助项目 | Scientific and Technological Research Program of Chongqing Municipal Education Commission[KJQN202001304] ; Scientific and Technological Research Program of Chongqing Municipal Education Commission[HZ2021013] ; Scientific and Technological Research Program of Chongqing Municipal Education Commission[KJZD-K202001305] ; Natural Science Foundation of Chongqing[cstc2020jcyj-msxmX0103] ; Natural Science Foundation of Yongchuan[2022yc-jckx20011] ; Natural Science Foundation of Yongchuan[2022yc-jckx20017] ; Foundation of Chongqing University of Arts and Sciences[P2020CL02] |
WOS研究方向 | Engineering ; Materials Science ; Physics |
语种 | 英语 |
WOS记录号 | WOS:000865910300011 |
出版者 | SPRINGER |
资助机构 | Scientific and Technological Research Program of Chongqing Municipal Education Commission ; Natural Science Foundation of Chongqing ; Natural Science Foundation of Yongchuan ; Foundation of Chongqing University of Arts and Sciences |
源URL | [http://ir.ipe.ac.cn/handle/122111/54989] ![]() |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Xiao, Wei |
作者单位 | 1.Chongqing Univ Arts & Sci, Sch Mat Sci & Engn, Chongqing 402160, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Jiang, Qinglin,Xian, Xiaobin,Xiao, Wei,et al. Template-Assisted Synthesis of Porous Manganese Dioxide Hollow Rods as Supercapacitor Electrode Material[J]. JOURNAL OF ELECTRONIC MATERIALS,2022:11. |
APA | Jiang, Qinglin.,Xian, Xiaobin.,Xiao, Wei.,Zhang, Yanhua.,Deng, Ying.,...&Qu, Jingkui.(2022).Template-Assisted Synthesis of Porous Manganese Dioxide Hollow Rods as Supercapacitor Electrode Material.JOURNAL OF ELECTRONIC MATERIALS,11. |
MLA | Jiang, Qinglin,et al."Template-Assisted Synthesis of Porous Manganese Dioxide Hollow Rods as Supercapacitor Electrode Material".JOURNAL OF ELECTRONIC MATERIALS (2022):11. |
入库方式: OAI收割
来源:过程工程研究所
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