Application of Pt loaded graphite felt in SO2-depolarized electrolyzer
文献类型：期刊论文
| 作者 | Ma, Xiaoshan1,2,3; Ding, Xifeng1; Sun, Xinliang1,2,3; Zhang, Ping1; Wang, Laijun1; Li, Yingxia3; Qu, Yongshui2; Chen, Songzhe1 |
| 刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
 |
| 出版日期 | 2022-08-29 |
| 卷号 | 47期号:74页码:31575-31586 |
| ISSN号 | 0360-3199 |
| 关键词 | Hydrogen production Hybrid sulfur (HyS) process SO2-depolarized electrolysis (SDE) Pt-loaded graphite felt Three-dimensional anode |
| DOI | 10.1016/j.ijhydene.2022.07.086 |
| 英文摘要 | The three-dimensional anodes for SO2 depolarized electrolysis (SDE) cells are prepared by loading Pt/C on high void content graphite felts, with the method of ultrasonic spray and vacuum suction. SEM results confirm the three-dimensional space distribution of Pt in graphite felts, which ensures sufficient contact between Pt/C and SO2 in anolyte. Comparing with the two-dimensional anodic catalyst layer loaded on the proton exchange membrane in a conventional SDE cell, the application of the three-dimensional anode decreases cell impedance greatly and improves the SDE performance significantly. In this study, 0.63 mg/cm(2) Pt loading amount shows the best performance when Pt/C is double-side-sprayed on graphite felt, and the current density reaches 1.24 A/cm(2) at cell voltage of 1.2 V, as operating at 60 ? and anolyte flow rate of 360 mL/min. The effects of the Pt loading amount, operating temperature and anolyte flow rate on the SDE performance are investigated. (C) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. |
| WOS关键词 | THIN-FILM ELECTROCATALYSTS ; AQUEOUS SULFUR-DIOXIDE ; HYDROGEN-PRODUCTION ; ELECTROCHEMICAL OXIDATION ; IN-SITU ; SO2 ; CYCLE ; DECOMPOSITION ; PERFORMANCE ; MEMBRANES |
| 资助项目 | National Key R & D Program of China[2018YFE0202001] ; Chinese National Science & Technology Major Project[ZX06901] ; Tsinghua University Initiative Scientific Research Program |
| WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels |
| 语种 | 英语 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| WOS记录号 | WOS:000864063400005 |
| 资助机构 | National Key R & D Program of China ; Chinese National Science & Technology Major Project ; Tsinghua University Initiative Scientific Research Program |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/55047]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Qu, Yongshui; Chen, Songzhe |
| 作者单位 | 1.Tsinghua Univ, Inst Nucl & New Energy Technol, Key Lab Adv Reactor Engn & Safety, Minist Educ, Beijing 100084, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China 3.Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Xiaoshan,Ding, Xifeng,Sun, Xinliang,et al. Application of Pt loaded graphite felt in SO2-depolarized electrolyzer[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2022,47(74):31575-31586. |
| APA | Ma, Xiaoshan.,Ding, Xifeng.,Sun, Xinliang.,Zhang, Ping.,Wang, Laijun.,...&Chen, Songzhe.(2022).Application of Pt loaded graphite felt in SO2-depolarized electrolyzer.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,47(74),31575-31586. |
| MLA | Ma, Xiaoshan,et al."Application of Pt loaded graphite felt in SO2-depolarized electrolyzer".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 47.74(2022):31575-31586. |
入库方式： OAI收割
来源：过程工程研究所
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