Simultaneous Extraction of Gold and Vanadium From Vanadium and Carbon-Rich Refractory Gold Minerals by Chlorination Roasting
文献类型:期刊论文
作者 | Liu, Shunliang1,2,3; Feng, Yali1; Li, Haoran2,3; Wang, Hongjun1,2 |
刊名 | METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE
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出版日期 | 2022-10-12 |
页码 | 12 |
ISSN号 | 1073-5615 |
DOI | 10.1007/s11663-022-02656-6 |
英文摘要 | To realize the efficient comprehensive utilization of refractory gold ore resources and environmental and economic gold extraction methods, this study investigated the optimal chlorine source for the sustained recovery of gold and vanadium from carbonaceous refractory gold ore by chlorination heat treatment. During the chlorination roasting process, the results indicated that CaCl2 has a greater chlorine supply capacity, and the reaction of refractory carbonaceous gold ore with CaCl2 was more intense than other chlorine sources. In addition, the effect of significant parameters (such as heat treatment temperature, heat treatment time, and CaCl2 additions) on gold and vanadium recovery ratios was carefully investigated. Under ideal conditions (i.e., CaCl2 concentration of 10 pct, heat treatment temperature of 1100 degrees C, heat treatment time of 4 hours, and air velocity of 1 L/min), 89.91 and 83.26 pct of gold and vanadium were recovered, respectively. In comparison, the main chemical mechanisms and phase transitions during the roasting process were studied by some analytical methods (such as scanning electron microscopy, energy dispersive spectroscopy, X-ray diffraction, and thermodynamic data). All alkaline chlorine sources were shown to destroy the structure of the minerals. CaCl2 was the compound with the more potent effect. Pyrite could enhance the chlorination of gold below 700 degrees C. In contrast, vanadium oxide could promote chlorination of gold above 700 degrees C. In addition, the leaching residue is primarily made of CaVO3, which can be used as a raw material for vanadium smelting. However, silicon dioxide and iron oxide will react at temperatures above 1100 degrees C, forming the "silicon oxygen" inclusion that hampered vanadium extraction. |
WOS关键词 | VALUABLE METALS ; CYANIDE ; KINETICS ; RECOVERY ; ASH ; ORE |
资助项目 | China Ocean Mineral Resource RD Association[JS-KTHT-2019-01] ; China Ocean Mineral Resource RD Association[DY135-B2-15] ; Major science and technology program for water pollution control and treatment[2015ZX07205-003] ; National Natural Science Foundation of China[21176242] ; National Natural Science Foundation of China[21176026] |
WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering |
语种 | 英语 |
WOS记录号 | WOS:000866315000003 |
出版者 | SPRINGER |
资助机构 | China Ocean Mineral Resource RD Association ; Major science and technology program for water pollution control and treatment ; National Natural Science Foundation of China |
源URL | [http://ir.ipe.ac.cn/handle/122111/55328] ![]() |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Liu, Shunliang |
作者单位 | 1.Univ Sci & Technol Beijing, Civil & Resource Engn Sch, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Shunliang,Feng, Yali,Li, Haoran,et al. Simultaneous Extraction of Gold and Vanadium From Vanadium and Carbon-Rich Refractory Gold Minerals by Chlorination Roasting[J]. METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE,2022:12. |
APA | Liu, Shunliang,Feng, Yali,Li, Haoran,&Wang, Hongjun.(2022).Simultaneous Extraction of Gold and Vanadium From Vanadium and Carbon-Rich Refractory Gold Minerals by Chlorination Roasting.METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE,12. |
MLA | Liu, Shunliang,et al."Simultaneous Extraction of Gold and Vanadium From Vanadium and Carbon-Rich Refractory Gold Minerals by Chlorination Roasting".METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE (2022):12. |
入库方式: OAI收割
来源:过程工程研究所
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