Energy-saving reactive pressure-swing distillation process for separation of methanol - dimethyl carbonate azeotrope via reacting with propylene oxide
文献类型：期刊论文
| 作者 | An, Ran1,2; Chen, Shengxin2; Li, Hao2,3; Li, Xinxin2,4; Jin, Ying2,4; Li, Chunhu1; An, Weizhong1; Liu, Ruixia2,3,4 |
| 刊名 | SEPARATION AND PURIFICATION TECHNOLOGY
 |
| 出版日期 | 2022-07-01 |
| 卷号 | 292页码:12 |
| 关键词 | Reactive distillation Pressure-swing distillation Methanol Heat integration Process simulation |
| ISSN号 | 1383-5866 |
| DOI | 10.1016/j.seppur.2022.120889 |
| 英文摘要 | Pressure-swing distillation (PSD) is a widely used in the chemical industry to separate azeotropes without the introduction of a any third component; however, the process involves high energy consumption and operating costs are required owing to the change in pressure. For the separation of methanol-dimethyl carbonate azeotropes, an intensified reactive pressure-swing distillation (R-PSD) process has been proposed, wherein a reactive distillation column is used, instead of a high-pressure column, and the propylene oxide (PO) is introduced into the system as a reactant to reacts with methonal. To compare the feasibility of the proposed R-PSD process with the conventional heat-integrated PSD process, three indicators-total energy requirements, total annual cost, and CO2 emissions-were used. The results show that the R-PSD process performs better than the conventional heat-integrated PSD process in terms of energy, economics and environmental owing to the partial consumption of methanol and the simultaneous co-production of high-value propylene glycol methyl ether (PGME). Moreover, at 50% methanol consumption, the total energy consumption, total annual cost, and the CO2 emissions were reduced by 46.0%, 34.3%, and 45.0%, respectively, compared with the conventional heat-integrated PSD process. This implies the improved R-PSD process has significant energy-saving potential. |
| WOS关键词 | HEAT INTEGRATION ; ETHYL-ACETATE ; DESIGN ; COLUMN ; SIMULATION ; EMISSIONS ; MEMBRANE ; REMOVAL ; MIXTURE ; WATER |
| 资助项目 | National Nature Science Foundation of China[21878315] ; K. C. Wong Education Foundation[GJTD2018-04] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000877059700001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Nature Science Foundation of China ; K. C. Wong Education Foundation |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/55370]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | An, Weizhong; Liu, Ruixia |
| 作者单位 | 1.Ocean Univ China, Dept Chem Engn, Qingdao 266100, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc,State Key, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China 4.Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450000, Peoples R China |
| 推荐引用方式 GB/T 7714 | An, Ran,Chen, Shengxin,Li, Hao,et al. Energy-saving reactive pressure-swing distillation process for separation of methanol - dimethyl carbonate azeotrope via reacting with propylene oxide[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2022,292:12. |
| APA | An, Ran.,Chen, Shengxin.,Li, Hao.,Li, Xinxin.,Jin, Ying.,...&Liu, Ruixia.(2022).Energy-saving reactive pressure-swing distillation process for separation of methanol - dimethyl carbonate azeotrope via reacting with propylene oxide.SEPARATION AND PURIFICATION TECHNOLOGY,292,12. |
| MLA | An, Ran,et al."Energy-saving reactive pressure-swing distillation process for separation of methanol - dimethyl carbonate azeotrope via reacting with propylene oxide".SEPARATION AND PURIFICATION TECHNOLOGY 292(2022):12. |
入库方式： OAI收割
来源：过程工程研究所
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