Ionic liquid enhancement of interface compatibility in mixed-linker ZIF-based mixed matrix membranes for advanced CO2/CH4 separation
文献类型：期刊论文
| 作者 | Gong, Lili1,2; Cai, Zhili2; Wu, Qi2; Liu, Lu2; Wang, Can2; Shan, Linglong2; Meng, Xianghai1; Luo, Shuangjiang2,3; Liu, Zhichang1; Zhang, Suojiang2 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2022-10-19 |
| 页码 | 10 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/d2ta05767k |
| 英文摘要 | Mixed matrix membranes (MMMs) are highly promising for natural gas sweetening due to their high microporosity and outstanding gas separation performance. However, MMMs are frequently challenged by the polymer/filler interfacial incompatibility, leading to the deterioration of gas separation performance. In this study, the mixed-linker ZIF-7-8 was employed as a filler by finely tuning the molecular sieving for CO2/CH4 separation. An amino-functionalized ionic liquid ([C(3)NH(2)Mim][Cl]) was introduced for constructing the interface connection between the ZIF-7-8 filler and polymer matrix through coordination and hydrogen bonding, which was verified by extended X-ray absorption fine structure (EXAFS) and electron paramagnetic resonance (EPR). The design of interface interaction through an IL is crucial to improve the interface compatibility and the CO2/CH4 separation performance. The newly developed 20% ZIF-7-8-IL (1%)/PI and 25% ZIF-7-8-IL (1%)/PI MMMs displayed a dramatic improvement of CO2 permeability by 244.2% and 291.6%, from 308 to 1060 and 1206 barrer, respectively, for pure-gas separation, compared to the pristine polyimide matrix. Moreover, the 25% ZIF-7-8-IL (1%)/PI MMM also demonstrated outstanding low-temperature mixed-gas CO2/CH4 separation performance in the temperature range of -45-35 degrees C, far beyond the 2018 mixed-gas CO2/CH4 upper bound. |
| WOS关键词 | GAS-SEPARATION ; PERMEATION PROPERTIES ; CONTAINING POLYIMIDE ; CO2 ; PERFORMANCE ; NANOCRYSTALS ; STABILITY ; POLYMER |
| 资助项目 | National Natural Science Foundation of China[22090063] ; National Natural Science Foundation of China[22008243] ; Dalian National Laboratory for Clean Energy (DNL) Cooperation Fund of CAS[DNL201917] ; Beijing Nova Program of Science and Technology[Z191100001119107] ; International Partner Program of the CAS[122111KYSB20200035] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000878279200001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China ; Dalian National Laboratory for Clean Energy (DNL) Cooperation Fund of CAS ; Beijing Nova Program of Science and Technology ; International Partner Program of the CAS |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/55382]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Luo, Shuangjiang; Liu, Zhichang; Zhang, Suojiang |
| 作者单位 | 1.China Univ Petr, Coll Chem Engn & Environm, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, Inst Proc Engn,State Key Lab Multiphase Complex S, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gong, Lili,Cai, Zhili,Wu, Qi,et al. Ionic liquid enhancement of interface compatibility in mixed-linker ZIF-based mixed matrix membranes for advanced CO2/CH4 separation[J]. JOURNAL OF MATERIALS CHEMISTRY A,2022:10. |
| APA | Gong, Lili.,Cai, Zhili.,Wu, Qi.,Liu, Lu.,Wang, Can.,...&Zhang, Suojiang.(2022).Ionic liquid enhancement of interface compatibility in mixed-linker ZIF-based mixed matrix membranes for advanced CO2/CH4 separation.JOURNAL OF MATERIALS CHEMISTRY A,10. |
| MLA | Gong, Lili,et al."Ionic liquid enhancement of interface compatibility in mixed-linker ZIF-based mixed matrix membranes for advanced CO2/CH4 separation".JOURNAL OF MATERIALS CHEMISTRY A (2022):10. |
入库方式： OAI收割
来源：过程工程研究所
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