Ultrahigh Capacity and Rapid Selective Recycling of Gold Ions by Organic Intercalated and Exfoliated Few-Layer Ti3C2TX Nanosheets
文献类型：期刊论文
| 作者 | Liu, Xiang1,2; Ma, Licheng3; Han, Pei-Wei3; Yang, Zongxian1,2; Li, Zhengchen1,2; Yan, Jingmin1,2; Wang, Yongliang4; Ye, Shufeng3 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2022-11-08 |
| 页码 | 14 |
| 关键词 | selective separation gold recycling adsorptive-reduction reutilization |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.2c05143 |
| 英文摘要 | For the sustainable development of the ecological environment in gold recycling, it is urgently desired to develop a more efficient and highly selective process for gold ions from e waste or mineral lixivium. As a kind of emerging two-dimensional nanomaterials, Ti3C2Tx has emerged as a rapidly developing novel water treatment material. Herein, the preparation of few-layer Ti3C2Tx nanosheets and their performance for recycling of gold ions were studied. Notably, it exhibits an impressive capacity of 2973.57 mg/g at room temperature, almost 124 times that of commercially available activated carbon (24 mg/g), and an exciting selectivity for Au(III) in the presence of competing ions due to perfectly weak reduction caused by the removal of the Al layer. The Langmuir isotherm and pseudo-second-order kinetic model can accurately depict the rapid adsorption process. Additionally, it can be regenerated effectively by thiourea and exhibits excellent reutilization. A critical mechanism involves an adsorptive-reduction pathway between Au(III) and active Ti sites. Excellent performance in real lixiviums from e-waste and gold-bearing sludge is also exhibited, demonstrating great potential for Au(III) recycling. It may be a sustainable direction for the capture and separation of Au(III) and also lays the foundation for the interface control of Ti3C2Tx and Au NPs as a catalyst and other functional materials. |
| WOS关键词 | RECOVERY ; MXENE ; ELECTRONICS ; ADSORPTION ; REMOVAL |
| 资助项目 | Innovation Academy for Green Manufacture, Chinese Academy of Sciences[IAGM-2019-A05] ; National Key RD Program[2019YFC1908405] ; National Key RD Program[2019YFC1907304] ; Chinese Academy of Sciences[XDA23030302] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000884446100001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Innovation Academy for Green Manufacture, Chinese Academy of Sciences ; National Key RD Program ; Chinese Academy of Sciences |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/55727]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Wang, Yongliang; Ye, Shufeng |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Innovat Acad Green Manufacture, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 4.Beijing Res Inst Chem Engn & Met, CNNC, Beijing 101149, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xiang,Ma, Licheng,Han, Pei-Wei,et al. Ultrahigh Capacity and Rapid Selective Recycling of Gold Ions by Organic Intercalated and Exfoliated Few-Layer Ti3C2TX Nanosheets[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2022:14. |
| APA | Liu, Xiang.,Ma, Licheng.,Han, Pei-Wei.,Yang, Zongxian.,Li, Zhengchen.,...&Ye, Shufeng.(2022).Ultrahigh Capacity and Rapid Selective Recycling of Gold Ions by Organic Intercalated and Exfoliated Few-Layer Ti3C2TX Nanosheets.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,14. |
| MLA | Liu, Xiang,et al."Ultrahigh Capacity and Rapid Selective Recycling of Gold Ions by Organic Intercalated and Exfoliated Few-Layer Ti3C2TX Nanosheets".ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022):14. |
入库方式： OAI收割
来源：过程工程研究所
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