Construction of Co3O4/CeO2 heterostructure nanoflowers facilitates deployment of oxygen defects to enhance the oxygen evolution kinetics
文献类型：期刊论文
| 作者 | Wang, Huan1; Zhang, Qiaoyan1; Sun, Fengmin1; Qi, Jian2; Zhang, Di1; Sun, Huilan1; Li, Zhaojin1; Wang, Qiujun1; Wang, Bo1 |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| 出版日期 | 2023-02-05 |
| 卷号 | 933页码:9 |
| 关键词 | Heterostructure nanoflowers Electronic behavior Interfaces Oxygen defects Oxygen evolution reaction |
| ISSN号 | 0925-8388 |
| DOI | 10.1016/j.jallcom.2022.167700 |
| 英文摘要 | The bottom-up design strategy can more rationally optimize the composition and structure of the materials to impart excellent oxygen evolution reaction (OER) performance. Heterostructures can modulate electronic behavior through interface construction to optimize materials properties for superior OER performance. In this paper, we created abundant Co3O4/CeO2 phase interfaces to tune the grain size, the electronic con-figuration of cobalt sites, and the content of oxygen defects in Co3O4, which increases the number of active sites, enhances the electronic conductivity of the material, and optimized the adsorption energy for reaction intermediates. Moreover, the assembly of nanograins into nanoflowers with a three-dimensional hier-archical pore structure can provide more effective active sites, abundant pores and channels for mass transport, and discrete cavities for in-depth reactions of intermediates. The construction of Co3O4/CeO2 heterostructure nanoflowers (CoCe HNFs) contributes to the excellent OER performance of the catalyst. (c) 2022 Elsevier B.V. All rights reserved. |
| WOS关键词 | NANOSHEETS ; ELECTROCATALYSTS ; SUPERCAPACITORS ; TRANSFORMATION ; COMPOSITES ; VACANCIES ; OXIDE |
| 资助项目 | National Natural Science Foundation of China ; Key Research and Development Program of Hebei Province ; Natural Science Foundation of Hebei Province ; Science Foundation of University of Hebei Province ; [22008053] ; [52002111] ; [51972306] ; [20310601D] ; [205A4401D] ; [E2022208023] ; [B2022208006] ; [B2021208061] ; [BJ2020053] ; [BJ2021001] |
| WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000883087800002 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | National Natural Science Foundation of China ; Key Research and Development Program of Hebei Province ; Natural Science Foundation of Hebei Province ; Science Foundation of University of Hebei Province |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/55764]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Qi, Jian; Wang, Qiujun; Wang, Bo |
| 作者单位 | 1.Hebei Univ Sci & Technol, Sch Mat Sci & Engn, Hebei Key Lab Flexible Funct Mat, Shijiazhuang 050000, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Huan,Zhang, Qiaoyan,Sun, Fengmin,et al. Construction of Co3O4/CeO2 heterostructure nanoflowers facilitates deployment of oxygen defects to enhance the oxygen evolution kinetics[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2023,933:9. |
| APA | Wang, Huan.,Zhang, Qiaoyan.,Sun, Fengmin.,Qi, Jian.,Zhang, Di.,...&Wang, Bo.(2023).Construction of Co3O4/CeO2 heterostructure nanoflowers facilitates deployment of oxygen defects to enhance the oxygen evolution kinetics.JOURNAL OF ALLOYS AND COMPOUNDS,933,9. |
| MLA | Wang, Huan,et al."Construction of Co3O4/CeO2 heterostructure nanoflowers facilitates deployment of oxygen defects to enhance the oxygen evolution kinetics".JOURNAL OF ALLOYS AND COMPOUNDS 933(2023):9. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。