The effect of ligand and acid promoter on hydroesterification of ethylene to methyl propionate and kinetic studies
文献类型：期刊论文
| 作者 | Wang, Luming1,2; Li, Zengxi1,2; Wang, Erqiang1; Li, Chunshan1,2,3 |
| 刊名 | MOLECULAR CATALYSIS
 |
| 出版日期 | 2022-12-01 |
| 卷号 | 533页码:11 |
| 关键词 | Ethylene Hydroesterification Phosphine ligand Electronic effect Reaction kinetics |
| ISSN号 | 2468-8231 |
| DOI | 10.1016/j.mcat.2022.112746 |
| 英文摘要 | A new palladium/tris(4-fluomphenyephosphine/p-toluenesulfonic acid catalytic system was developed to synthesize methyl propionate from ethylene hydroesterification. The influence of phosphine ligands and acid promoters on catalytic activity was systematically studied. A volcano relationship between the catalytic activity and the electric effect of phosphine ligand was achieved through the characterization of P-31 NMR of selenium phosphine compounds. An acid strength range favorable to the hydroesterification of ethylene was found by characterizing the pKa value of Brunsted acid. Then, the effect of phosphine ligand/Pd(OAc)(2) ratio, p-toluene-sulfonic/Pd(OAc)(2) ratio, temperature, time, and pressure on this reaction were investigated. Finally, the elementary reaction-based kinetic model was developed, which indicated that nucleophilic attack of methanol on the Pd-acyl intermediate to give methyl propionate is the rate-determining step. The activation barrier of rate-determining step is 83.1 kJ.mol(-1). |
| WOS关键词 | PALLADIUM-CATALYZED METHOXYCARBONYLATION ; CARBON-MONOXIDE ; IONIC DIPHOSPHINE ; CO-CATALYSIS ; EFFICIENT ; HYDROFORMYLATION ; COPOLYMERIZATION ; PHOSPHINE ; OLEFINS ; METHACRYLATE |
| 资助项目 | National Funds for Distinguished Young youths ; National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; [22025803] ; [22178338] ; [QYZDB-SSW-SLH022] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000882525700006 |
| 出版者 | ELSEVIER |
| 资助机构 | National Funds for Distinguished Young youths ; National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/55795]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Wang, Erqiang; Li, Chunshan |
| 作者单位 | 1.Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Natl Key Lab Clean & Efficient Coking Technol,Inst, Beijing 100190, Peoples R China 3.Huizhou Inst Green Energy & Adv Mat, Adv Energy Sci & Technol Guangdong Lab, Huizhou 516081, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Luming,Li, Zengxi,Wang, Erqiang,et al. The effect of ligand and acid promoter on hydroesterification of ethylene to methyl propionate and kinetic studies[J]. MOLECULAR CATALYSIS,2022,533:11. |
| APA | Wang, Luming,Li, Zengxi,Wang, Erqiang,&Li, Chunshan.(2022).The effect of ligand and acid promoter on hydroesterification of ethylene to methyl propionate and kinetic studies.MOLECULAR CATALYSIS,533,11. |
| MLA | Wang, Luming,et al."The effect of ligand and acid promoter on hydroesterification of ethylene to methyl propionate and kinetic studies".MOLECULAR CATALYSIS 533(2022):11. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。