Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity
文献类型：期刊论文
| 作者 | Shi, Benbing2; Pang, Xiao2; Li, Shunning3; Wu, Hong2,4; Shen, Jianliang2; Wang, Xiaoyao2; Fan, Chunyang2; Cao, Li2; Zhu, Tianhao2; Qiu, Ming2 |
| 刊名 | NATURE COMMUNICATIONS
 |
| 出版日期 | 2022-11-05 |
| 卷号 | 13期号:1页码:9 |
| DOI | 10.1038/s41467-022-33868-8 |
| 英文摘要 | The idea of spatial confinement has gained widespread interest in myriad applications. Especially, the confined short hydrogen-bond (SHB) network could afford an attractive opportunity to enable proton transfer in a nearly barrierless manner, but its practical implementation has been challenging. Herein, we report a SHB network confined on the surface of ionic covalent organic framework (COF) membranes decorated by densely and uniformly distributed hydrophilic ligands. Combined experimental and theoretical evidences have pointed to the confinement of water molecules allocated to each ligand, achieving the local enrichment of hydronium ions and the concomitant formation of SHBs in water-hydronium domains. These overlapped water-hydronium domains create an interconnected SHB network, which yields an unprecedented ultrahigh proton conductivity of 1389 mS cm(-1) at 90 degrees C, 100% relative humidity. When hydronium ions are enriched in confined water, short hydrogen bonds (SHBs) form due to the constrained space of excess protons between pairs of water molecules. Here authors demonstrate a SHB network confined on the surface of ionic COF membranes with tunable -SO3H groups, with proton conductivity of 1389 mS cm(-1) at 90 C-o. |
| WOS关键词 | COVALENT ORGANIC FRAMEWORKS ; SULFONIC-ACID GROUPS ; MOLECULAR-DYNAMICS ; WATER ; TRANSPORT ; INTERFACE ; MECHANISM ; MEMBRANE ; SYSTEMS |
| 资助项目 | National Natural Science Foundation of China[91934302] ; National Natural Science Foundation of China[21961142013] ; Program of Introducing Talents of Discipline to Universities[BP0618007] |
| WOS研究方向 | Science & Technology - Other Topics |
| 语种 | 英语 |
| 出版者 | NATURE PORTFOLIO |
| WOS记录号 | WOS:000879737500018 |
| 资助机构 | National Natural Science Foundation of China ; Program of Introducing Talents of Discipline to Universities |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/55839]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Pan, Feng; Jiang, Zhongyi |
| 作者单位 | 1.Tianjin Univ, Zhejiang Inst, Ningbo 315201, Zhejiang, Peoples R China 2.Tianjin Univ, Sch Chem Engn & Technol, Key Lab Green Chem Technol, Minist Educ, Tianjin 300072, Peoples R China 3.Peking Univ, Sch Adv Mat, Shenzhen Grad Sch, Shenzhen 518055, Guangdong, Peoples R China 4.Haihe Lab Sustainable Chem Transformat, Tianjin 300192, Peoples R China 5.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn,State Key Lab Multi, Beijing 100190, Peoples R China 6.Tianjin Univ, Joint Sch Natl Univ Singapore & Tianjin Univ, Int Campus, Fuzhou 350207, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Benbing,Pang, Xiao,Li, Shunning,et al. Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity[J]. NATURE COMMUNICATIONS,2022,13(1):9. |
| APA | Shi, Benbing.,Pang, Xiao.,Li, Shunning.,Wu, Hong.,Shen, Jianliang.,...&Jiang, Zhongyi.(2022).Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity.NATURE COMMUNICATIONS,13(1),9. |
| MLA | Shi, Benbing,et al."Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity".NATURE COMMUNICATIONS 13.1(2022):9. |
入库方式： OAI收割
来源：过程工程研究所
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