Length A novel pathway for the preparation of Mg metal from magnesia
文献类型：期刊论文
| 作者 | Zhang, Zhimin; Lu, Xuchen; Yan, Yan |
| 刊名 | JOURNAL OF MAGNESIUM AND ALLOYS
 |
| 出版日期 | 2022-10-01 |
| 卷号 | 10期号:10页码:2847-2856 |
| 关键词 | Magnesium Electrolysis Anhydrous magnesium chloride Hydrolysis |
| ISSN号 | 2213-9567 |
| DOI | 10.1016/j.jma.2021.02.0092213-9567 |
| 英文摘要 | High-purity anhydrous magnesium chloride was prepared from magnesia and ammonium chloride. The chlorination process was analyzed and then the critical stages affecting the purity of anhydrous magnesium chloride were pinpointed. The effect of sample dimension on the above critical stages was investigated respectively. The purity guarantee mechanism of anhydrous magnesium chloride was proposed. After that, magnesium metal was obtained via electrolyzing the anhydrous magnesium chloride-containing molten salt. The new process for the continuous production of magnesium metal from magnesia was proposed and discussed. The incomplete chlorination reaction and the hydrolysis of anhydrous magnesium chloride are the two critical stages affecting the purity of the anhydrous magnesium chloride. The dimension of the sample can influence reaction process and reaction mechanism, and thus the problems of incomplete chlorination reaction and hydrolysis can be solved together. The magnesia content in anhydrous magnesium chloride was below 0.1 wt.% when the ratio of height to diameter of the sample was over 2.43. The content of impurities in the magnesium metal obtained met the specifications of the product Mg9980. The current efficiency was (94.7 +/- 1.8)% and the electricity consumption was (9107 +/- 97) kW h/t. (c) 2021 Chongqing University. Publishing services provided by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license ( http://creativecommons.org/licenses/by-nc-nd/4.0/ ) Peer review under responsibility of Chongqing University |
| WOS关键词 | CHLORIDE ; MGCL2-CENTER-DOT-6H(2)O ; DEHYDRATION |
| 资助项目 | National Natural Sci-ence Foundation of China ; Autonomous Re-search Fund of State Key Laboratory of Multiphase Complex Systems ; [51501178] ; [MPCS-2019-A-10] |
| WOS研究方向 | Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000889792900001 |
| 出版者 | KEAI PUBLISHING LTD |
| 资助机构 | National Natural Sci-ence Foundation of China ; Autonomous Re-search Fund of State Key Laboratory of Multiphase Complex Systems |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/55864]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Lu, Xuchen |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zhimin,Lu, Xuchen,Yan, Yan. Length A novel pathway for the preparation of Mg metal from magnesia[J]. JOURNAL OF MAGNESIUM AND ALLOYS,2022,10(10):2847-2856. |
| APA | Zhang, Zhimin,Lu, Xuchen,&Yan, Yan.(2022).Length A novel pathway for the preparation of Mg metal from magnesia.JOURNAL OF MAGNESIUM AND ALLOYS,10(10),2847-2856. |
| MLA | Zhang, Zhimin,et al."Length A novel pathway for the preparation of Mg metal from magnesia".JOURNAL OF MAGNESIUM AND ALLOYS 10.10(2022):2847-2856. |
入库方式： OAI收割
来源：过程工程研究所
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