Nanobubbles nucleation and mechanistic analysis of ionic liquids aqueous solutions by in-situ liquid cell transmission electron microscopy
文献类型：期刊论文
| 作者 | Liu, Guliang1,2,3; Ding, Weilu1,2; Wang, Ling1; Wu, Hui1; Bai, Lu1,2,3; Diao, Yanyan1,2,3; Zhang, Xiangping1,2,3 |
| 刊名 | JOURNAL OF MOLECULAR LIQUIDS
 |
| 出版日期 | 2022-11-15 |
| 卷号 | 366页码:13 |
| 关键词 | Nanobubbles nucleation In-situ TEM Ionic Liquids Water radiolysis |
| ISSN号 | 0167-7322 |
| DOI | 10.1016/j.molliq.2022.120130 |
| 英文摘要 | Hydrogen generation by metal-free photocatalysts and electrocatalysis of H2O is currently deemed as one of the most innovative and challenging routes to obtain sustainable green energy. Due to the high tunability, ionic liquids are expected to be new generation catalysts for H-2 production. In this work, for the first time, the dynamic behavior of nanobubbles formed from water radiolysis promoted by ionic liquids [C(n)mim][BF4] and [C(n)mim][PF6] was observed by in-situ transmission electron microscopy in liquid cells at nanoscale resolution. Aided by density functional theory and molecular dynamics simulations, we attribute the primary underlying mechanism to the activation of the hydrogen atoms of the water molecule by the anions [BF4-] and [PF6-] in the ionic liquids. We conclude that our experiment will shed light on developing new ionic liquids that may further increase the yield of hydrogen production from photolytic and electrolytic water, and consequentially promises to reduce energy consumption and promote new developments in clean energy. (C) 2022 Elsevier B.V. All rights reserved. |
| WOS关键词 | HYDROGEN EVOLUTION ; GROWTH ; MULTISCALE ; RADIOLYSIS ; CATALYSTS ; AIR |
| 资助项目 | National Natural Science Foundation of China[21676280] ; National Natural Science Foundation of China[21978292] ; National Natural Science Foundation of China[21476239] ; Key Research Program of Chinese Academy of Sciences[ZDRW-ZS-2018-1-3] ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences[IAGM2020C20] ; Instrument Developing Project of the Chinese Academy of Sciences[YJKYYQ20200062] |
| WOS研究方向 | Chemistry ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000888875100009 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; Key Research Program of Chinese Academy of Sciences ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences ; Instrument Developing Project of the Chinese Academy of Sciences |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/55967]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Diao, Yanyan |
| 作者单位 | 1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn, CAS Key Lab Green Proc & Engn,State Key Lab Multi, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Coll Chem & Engn, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Innovat Acad Green Mfg, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Guliang,Ding, Weilu,Wang, Ling,et al. Nanobubbles nucleation and mechanistic analysis of ionic liquids aqueous solutions by in-situ liquid cell transmission electron microscopy[J]. JOURNAL OF MOLECULAR LIQUIDS,2022,366:13. |
| APA | Liu, Guliang.,Ding, Weilu.,Wang, Ling.,Wu, Hui.,Bai, Lu.,...&Zhang, Xiangping.(2022).Nanobubbles nucleation and mechanistic analysis of ionic liquids aqueous solutions by in-situ liquid cell transmission electron microscopy.JOURNAL OF MOLECULAR LIQUIDS,366,13. |
| MLA | Liu, Guliang,et al."Nanobubbles nucleation and mechanistic analysis of ionic liquids aqueous solutions by in-situ liquid cell transmission electron microscopy".JOURNAL OF MOLECULAR LIQUIDS 366(2022):13. |
入库方式： OAI收割
来源：过程工程研究所
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