Fine Pore-Structure Engineering by Ligand Conformational Control of Naphthalene Diimide-Based Semiconducting Porous Coordination Polymers for Efficient Chemiresistive Gas Sensing
文献类型：期刊论文
| 作者 | Xue, Ziqian2; Zheng, Jia-Jia1; Nishiyama, Yusuke3,4; Yao, Ming-Shui2,5; Aoyama, Yoshitaka4; Fan, Zeyu2; Wang, Ping; Kajiwara, Takashi2; Kubota, Yoshiki6; Horike, Satoshi2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2022-12-07 |
| 页码 | 6 |
| ISSN号 | 1433-7851 |
| 关键词 | PCPs MOFs NDI Semiconductors Sensors 3D electron diffraction (3D ED) |
| DOI | 10.1002/anie.202215234 |
| 英文摘要 | Exploring new porous coordination polymers (PCPs) that have tunable structure and conductivity is attractive but remains challenging. Herein, fine pore structure engineering by ligand conformation control of naphthalene diimide (NDI)-based semiconducting PCPs with pi stacking-dependent conductivity tunability is achieved. The pi stacking distances and ligand conformation in these isoreticular PCPs were modulated by employing metal centers with different coordination geometries. As a result, three conjugated PCPs (Co-pyNDI, Ni-pyNDI, and Zn-pyNDI) with varying pore structure and conductivity were obtained. Their crystal structures were determined by three-dimensional electron diffraction. The through-space charge transfer and tunable pore structure in these PCPs result in modulated selectivity and sensitivity in gas sensing. Zn-pyNDI can serve as a room-temperature operable chemiresistive sensor selective to acetone. |
| WOS关键词 | METAL-ORGANIC FRAMEWORK ; CONDUCTIVITY |
| 资助项目 | Japan Society of the Promotion of Science (JSPS)[JP18H05262] ; Japan Society of the Promotion of Science (JSPS)[JP22H05005] ; Japan Society of the Promotion of Science (JSPS)[JP22K05128] ; International Research Fellow of JSPS[P20340] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000893533900001 |
| 资助机构 | Japan Society of the Promotion of Science (JSPS) ; International Research Fellow of JSPS |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/56066]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Otake, Ken-ichi; Kitagawa, Susumu |
| 作者单位 | 1.Natl Ctr Nanosci & Technol China, Lab Theoret & Computat Nanosci, Beijing 100190, Peoples R China 2.Kyoto Univ, Inst Integrated Cell Mat Sci, Inst Adv Study, Ushinomiya cho,Sakyo ku, Kyoto 6068501, Japan 3.RIKEN JEOL Collaborat Ctr, Yokohama, Kanagawa 2300045, Japan 4.JEOL Ltd, Akishima, Tokyo 1968558, Japan 5.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Zhongguancun Beiertiao 1, Beijing 100190, Peoples R China 6.Osaka Metropolitan Univ, Grad Sch Sci, Dept Phys, Osaka 5998531, Japan |
| 推荐引用方式 GB/T 7714 | Xue, Ziqian,Zheng, Jia-Jia,Nishiyama, Yusuke,et al. Fine Pore-Structure Engineering by Ligand Conformational Control of Naphthalene Diimide-Based Semiconducting Porous Coordination Polymers for Efficient Chemiresistive Gas Sensing[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022:6. |
| APA | Xue, Ziqian.,Zheng, Jia-Jia.,Nishiyama, Yusuke.,Yao, Ming-Shui.,Aoyama, Yoshitaka.,...&Kitagawa, Susumu.(2022).Fine Pore-Structure Engineering by Ligand Conformational Control of Naphthalene Diimide-Based Semiconducting Porous Coordination Polymers for Efficient Chemiresistive Gas Sensing.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,6. |
| MLA | Xue, Ziqian,et al."Fine Pore-Structure Engineering by Ligand Conformational Control of Naphthalene Diimide-Based Semiconducting Porous Coordination Polymers for Efficient Chemiresistive Gas Sensing".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022):6. |
入库方式： OAI收割
来源：过程工程研究所
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