The critical role of steam during activation process on the catalytic performance of VPO for n-butane selective oxidation to maleic anhydride
文献类型：期刊论文
| 作者 | Zhang, Yongkang1; Zhang, Ruirui1; Dong, Jie1; Wu, Yuchao4; Luo, Chen4; Zhang, Haotian4; Zhu, Shengwen1,2; Liu, Ruixia1,2,3 |
| 刊名 | JOURNAL OF CATALYSIS
 |
| 出版日期 | 2022-12-01 |
| 卷号 | 416页码:157-169 |
| 关键词 | VPO catalyst Steam Activation process N-butane Maleic anhydride Lewis acid site |
| ISSN号 | 0021-9517 |
| DOI | 10.1016/j.jcat.2022.11.004 |
| 英文摘要 | Vanadium phosphorus oxide (VPO) catalyst activation method is essential for the catalytic oxidation form n-butane to maleic anhydride. Here, we evaluate the effect of steam content on VPO catalyst during the activation process and validate the adjustment of the steam content could modulate the VPO activity. The DRIFTS results reveal that the steam content governs the formation of P-OH and V-OH species on the surface of VPO catalyst, whereas these sites would not enhance the catalytic activity directly. In contrast, the L acid site V5+-O-P=O, forming a mutual transformation relationship with the P-OH species under steam/O-2 conditions, is the main active site that dominates the conversion of n-butane, and a moderate amount of steam plays a role in stabilizing the V5+-O-P=O site. (C) 2022 Elsevier Inc. All rights reserved. |
| WOS关键词 | VANADYL PYROPHOSPHATE CATALYSTS ; ACTIVE PHASE ; PHOSPHATE ; SURFACE ; REACTIVITY ; MECHANISM ; METHANE ; OXIDE ; FUNCTIONALIZATION ; TRANSFORMATION |
| 资助项目 | National Science Fund for Excellent Young Scholars[22222813] ; Joint Fund of Yulin University ; Dalian National Laboratory for Clean Energy[2021016] ; Key Scientific and Technological Projects in Huizhou[2021JBZ5.1] |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000898100000013 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 资助机构 | National Science Fund for Excellent Young Scholars ; Joint Fund of Yulin University ; Dalian National Laboratory for Clean Energy ; Key Scientific and Technological Projects in Huizhou |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/56141]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Liu, Ruixia |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc,CAS Key La, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450000, Peoples R China 4.Petrochem Res Inst CNPC, Beijing 1022066, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yongkang,Zhang, Ruirui,Dong, Jie,et al. The critical role of steam during activation process on the catalytic performance of VPO for n-butane selective oxidation to maleic anhydride[J]. JOURNAL OF CATALYSIS,2022,416:157-169. |
| APA | Zhang, Yongkang.,Zhang, Ruirui.,Dong, Jie.,Wu, Yuchao.,Luo, Chen.,...&Liu, Ruixia.(2022).The critical role of steam during activation process on the catalytic performance of VPO for n-butane selective oxidation to maleic anhydride.JOURNAL OF CATALYSIS,416,157-169. |
| MLA | Zhang, Yongkang,et al."The critical role of steam during activation process on the catalytic performance of VPO for n-butane selective oxidation to maleic anhydride".JOURNAL OF CATALYSIS 416(2022):157-169. |
入库方式： OAI收割
来源：过程工程研究所
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