Delicate Co-Control of Shell Structure and Sulfur Vacancies in Interlayer-Expanded Tungsten Disulfide Hollow Sphere for Fast and Stable Sodium Storage
文献类型：期刊论文
| 作者 | Zhang, Xing1; Bi, Ruyi1,2; Wang, Jiangyan2; Zheng, Meng3; Wang, Jin3; Yu, Ranbo1,4; Wang, Dan2 |
| 刊名 | ADVANCED MATERIALS
 |
| 出版日期 | 2022-12-18 |
| 页码 | 9 |
| ISSN号 | 0935-9648 |
| 关键词 | expanded interlayer spacing hollow multishelled structure sodium storage sulfur vacancies transition-metal sulfides |
| DOI | 10.1002/adma.202209354 |
| 英文摘要 | Hollow multishelled structure (HoMS) is a promising multi-functional platform for energy storage, owing to its unique temporal-spatial ordering property and buffering function. Accurate co-control of its multiscale structures may bring fascinating properties and new opportunities, which is highly desired yet rarely achieved due to the challenging synthesis. Herein, a sequential sulfidation and etching approach is developed to achieve the delicate co-control over both molecular- and nano-/micro-scale structure of WS2-x HoMS. Typically, sextuple-shelled WS2-x HoMS with abundant sulfur vacancies and expanded-interlayer spacing is obtained from triple-shelled WO3 HoMS. By further coating with nitrogen-doped carbon, WS2-x HoMS maintains a reversible capacity of 241.7 mAh g(-1) at 5 A g(-1) after 1000 cycles for sodium storage, which is superior to the previously reported results. Mechanism analyses reveal that HoMS provides good electrode-electrolyte contact and plentiful sodium storage sites as well as an effective buffer of the stress/strain during cycling; sulfur vacancy and expanded interlayer of WS2-x enhance ion diffusion kinetics; carbon coating improves the electron conductivity and benefits the structural stability. This finding offers prospects for realizing practical fast-charging, high-energy, and long-cycling sodium storage. |
| WOS关键词 | RATIONAL DESIGN ; PERFORMANCE ; WS2 |
| 资助项目 | Natural Science Foundation of China[51932001] ; Natural Science Foundation of China[51872024] ; Natural Science Foundation of China[21820102002] ; Natural Science Foundation of China[21931012] ; National Key RD Program[2018YFA0703503] ; National Key RD Program[2021YFC2902500] ; Cooperation Fund of the Institute of Clean Energy Innovation, Chinese Academy of Sciences[DNL202020] ; Zhongke-Yuneng Joint R&D Center Program[ZKYN2022008] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000899642500001 |
| 资助机构 | Natural Science Foundation of China ; National Key RD Program ; Cooperation Fund of the Institute of Clean Energy Innovation, Chinese Academy of Sciences ; Zhongke-Yuneng Joint R&D Center Program |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/56180]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Wang, Jiangyan; Yu, Ranbo; Wang, Dan |
| 作者单位 | 1.Univ Sci & Technol Beijing, Sch Met & Ecol Engn, Dept Phys Chem, 30 Xueyuan Rd, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, 1 North 2nd St, Beijing 100190, Peoples R China 3.Shenzhen Univ, Coll Mat Sci & Engn, 1066 Xueyuan Ave, Shenzhen 518000, Peoples R China 4.Zhengzhou Univ, Key Lab Adv Mat Proc & Mold, Minist Educ, Zhengzhou 450002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xing,Bi, Ruyi,Wang, Jiangyan,et al. Delicate Co-Control of Shell Structure and Sulfur Vacancies in Interlayer-Expanded Tungsten Disulfide Hollow Sphere for Fast and Stable Sodium Storage[J]. ADVANCED MATERIALS,2022:9. |
| APA | Zhang, Xing.,Bi, Ruyi.,Wang, Jiangyan.,Zheng, Meng.,Wang, Jin.,...&Wang, Dan.(2022).Delicate Co-Control of Shell Structure and Sulfur Vacancies in Interlayer-Expanded Tungsten Disulfide Hollow Sphere for Fast and Stable Sodium Storage.ADVANCED MATERIALS,9. |
| MLA | Zhang, Xing,et al."Delicate Co-Control of Shell Structure and Sulfur Vacancies in Interlayer-Expanded Tungsten Disulfide Hollow Sphere for Fast and Stable Sodium Storage".ADVANCED MATERIALS (2022):9. |
入库方式： OAI收割
来源：过程工程研究所
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