Cooperative catalytic effects between the penta-coordinated Al and Al2O3 in Al2O3-AlPO4 for aldol condensation of methyl acetate with formaldehyde to methyl acrylate
文献类型：期刊论文
| 作者 | Wu, Zhenyu1,2; Li, Zengxi1,2; Li, Chunshan1,2,3 |
| 刊名 | CHINESE JOURNAL OF CHEMICAL ENGINEERING
 |
| 出版日期 | 2022-12-01 |
| 卷号 | 52页码:172-183 |
| 关键词 | Methyl acrylate (MA) Aldol condensation Penta-coordinated aluminum Cooperative effects |
| ISSN号 | 1004-9541 |
| DOI | 10.1016/j.cjche.2021.11.025 |
| 英文摘要 | The bare amorphous Al2O3-AlPO4 and Cs/Al2O3-AlPO4 catalysts were developed for the aldol condensa-tion of methyl acetate with formaldehyde to methyl acrylate. The structure and property of catalyst were characterized by XRD, XPS, BET, Pyridine-IR, FT-IR, 27Al-MASNMR, NH3-/CO2-TPD and SEM. The correla-tion between structural features and acid-base properties was established, and the loading effect of the cesium species was investigated. Due to cooperative catalytic effects between the penta-coordinated Al and Al2O3, the weak-II acid and medium acid site densities and the product selectivity were improved. While the basic site densities of these catalysts were almost in proportion to the conversion of methyl acetate. The loaded Cs could form new basic sites and change the distribution of acid sites which further enhance the catalytic performance. As a result, the 10Cs/8AlP was proved to be an optimal catalyst with the yield and selectivity of 21.2% and 85% for methyl acrylate respectively. During the reaction, a deac-tivation behavior was observed on 10Cs/8AlP catalyst due to the carbon deposition, however, it could be regenerated by thermal treatment in the air atmosphere at 400 degrees C.(c) 2022 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd. All rights reserved. |
| WOS关键词 | METAL-SUPPORT INTERACTION ; ALUMINUM PHOSPHATE ; MESOPOROUS ALPO4 ; CESIUM OXIDE ; PHASE ; OXIDATION ; METHANOL ; ZEOLITE ; ACID ; DEHYDRATION |
| 资助项目 | Key Research Program of Frontier Sciences[QYZDB-SSW-SLH022] ; National Natural Science Foundation of China[21676270] ; National Natural Science Foundation of China[21878293] ; National Natural Science Foundation of China[22178338] ; Joint Fund of the Yulin University ; Dalian National-Laboratory for Clean Energy[2021018] ; Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering[2017-K08] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000902231800014 |
| 出版者 | CHEMICAL INDUSTRY PRESS CO LTD |
| 资助机构 | Key Research Program of Frontier Sciences ; National Natural Science Foundation of China ; Joint Fund of the Yulin University ; Dalian National-Laboratory for Clean Energy ; Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/56325]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Li, Zengxi; Li, Chunshan |
| 作者单位 | 1.Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Beijing Key Lab Ion Liq, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Zhongke Langfang Inst Proc Engn, Shijiazhuang 065000, Hebei, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Zhenyu,Li, Zengxi,Li, Chunshan. Cooperative catalytic effects between the penta-coordinated Al and Al2O3 in Al2O3-AlPO4 for aldol condensation of methyl acetate with formaldehyde to methyl acrylate[J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING,2022,52:172-183. |
| APA | Wu, Zhenyu,Li, Zengxi,&Li, Chunshan.(2022).Cooperative catalytic effects between the penta-coordinated Al and Al2O3 in Al2O3-AlPO4 for aldol condensation of methyl acetate with formaldehyde to methyl acrylate.CHINESE JOURNAL OF CHEMICAL ENGINEERING,52,172-183. |
| MLA | Wu, Zhenyu,et al."Cooperative catalytic effects between the penta-coordinated Al and Al2O3 in Al2O3-AlPO4 for aldol condensation of methyl acetate with formaldehyde to methyl acrylate".CHINESE JOURNAL OF CHEMICAL ENGINEERING 52(2022):172-183. |
入库方式： OAI收割
来源：过程工程研究所
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