High Dispersed Pd, Pt Supported on La, Ce-Alumina for Excellent Low Temperature Toluene Oxidation: Effect of Calcination Temperature and Ascorbic Acid Reduction
文献类型：期刊论文
| 作者 | Wang, Tao1,2; Li, Shuangde2; Chen, Su1; Chai, Shaohua2,3; Zhou, Mu4; Nie, Linfeng2; Chen, Yunfa2,3,5 |
| 刊名 | CATALYSIS LETTERS
 |
| 出版日期 | 2022-12-30 |
| 页码 | 12 |
| 关键词 | Calcination temperature Ascorbic acid reduction Toluene oxidation Adsorbed surface oxygen Structure sensitivity |
| ISSN号 | 1011-372X |
| DOI | 10.1007/s10562-022-04253-3 |
| 英文摘要 | Seeking highly dispersed noble metals catalysts with varied valence, together with oxygen species and Lewis acid regulation are an important way to meet high efficiency toluene oxidation. Herein, the catalyst of 1 wt.% Pt and 1 wt.% Pd loaded on Al2O3 modified with La, Ce (PtPd/LCA), is synthesized through the adjustment of different calcination temperature from 250 to 550 ? under ascorbic acid reduction. Their redox, surface oxygen species, surface species acid properties and reaction mechanism were systematically characterized by H-2-TPR, O-2-TPD, XPS, pyridine-IR and in-situ DRIFTS. PtPd/LCA-250 totally eliminats toluene at 175 ? under 60,000 mL(-1) g(-1) h(-1), together with superior water resistance and stable performance. Lower calcinated temperature and reduction of ascorbic acid, which leading to the proper co-existence of Pd and PdO, together with the abundant surface chemically adsorbed oxygen species and Lewis acid sites, is responsible for better catalytic activity. The catalyst could be a step forward in designing efficient and facile technologies for abatement of VOCs. |
| WOS关键词 | CATALYTIC PERFORMANCE ; SULFUR RESISTANCE ; SINGLE-ATOM ; PALLADIUM ; PLATINUM ; BENZENE ; CO ; COMBUSTION ; STABILITY ; METHANE |
| 资助项目 | National Key R & D Program of China[2022YFC3702800] ; Strategic Priority Research Program (A) of the Chinese Academy of Sciences[XDA23030300] ; State Key Laboratory of Multiphase complex systems[MPCS-2021-A-01] ; Youth Innovation Promotion Association of Chinese Academy of Sciences[2018062] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000906087600001 |
| 出版者 | SPRINGER |
| 资助机构 | National Key R & D Program of China ; Strategic Priority Research Program (A) of the Chinese Academy of Sciences ; State Key Laboratory of Multiphase complex systems ; Youth Innovation Promotion Association of Chinese Academy of Sciences |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/56377]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Li, Shuangde; Chen, Yunfa |
| 作者单位 | 1.Nanjing Tech Univ, Coll Chem Engn, State Key Lab Mat Oriented Chem Engn, Jiangsu Key Lab Fine Chem & Funct Polymer Mat, Nanjing 210009, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multi Phase Complex Syst, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China 4.Beijing Inst Petrochem Technol, Beijing 102617, Peoples R China 5.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Tao,Li, Shuangde,Chen, Su,et al. High Dispersed Pd, Pt Supported on La, Ce-Alumina for Excellent Low Temperature Toluene Oxidation: Effect of Calcination Temperature and Ascorbic Acid Reduction[J]. CATALYSIS LETTERS,2022:12. |
| APA | Wang, Tao.,Li, Shuangde.,Chen, Su.,Chai, Shaohua.,Zhou, Mu.,...&Chen, Yunfa.(2022).High Dispersed Pd, Pt Supported on La, Ce-Alumina for Excellent Low Temperature Toluene Oxidation: Effect of Calcination Temperature and Ascorbic Acid Reduction.CATALYSIS LETTERS,12. |
| MLA | Wang, Tao,et al."High Dispersed Pd, Pt Supported on La, Ce-Alumina for Excellent Low Temperature Toluene Oxidation: Effect of Calcination Temperature and Ascorbic Acid Reduction".CATALYSIS LETTERS (2022):12. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。