Adsorption of volatile benzene series compounds by surface-modified glass fibers: kinetics, thermodynamic adsorption efficiencies, and mechanisms
文献类型:期刊论文
作者 | Guo, Rui; Jiang, Sijing; Hu, Ming; Zhan, Yuhang; Cheng, Kun; Duan, Gaigai |
刊名 | ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
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出版日期 | 2021-06 |
卷号 | 28期号:24页码:30898-30907 |
关键词 | Modified glass fibers Volatile benzene series compounds Kinetics adsorption efficiencies Thermodynamic adsorption efficiencies Adsorption mechanisms |
ISSN号 | 0944-1344 |
英文摘要 | The presence of volatile benzene series compounds (VBSCs) in the environment is continually increasing, with the potential for negative effects on human health. It is therefore important to develop new materials for the adsorption of these compounds using various modification techniques. Glass fibers are a promising adsorbent for VBSCs and offer a number of advantages. In the present work, the surfaces of glass fibers were modified using hydrogen peroxide, a sodium hydroxide solution, or Piranha solution (a mixture of concentrated sulfuric acid and hydrogen peroxide). The adsorption characteristics of the resulting specimens were investigated, employing 10 volatile benzene-based compounds, and the activated glass fibers showed significantly improved adsorption efficiencies. The fibers activated with the Piranha solution were further modified with a triethoxysilyl benzene compound to obtain an aryl-modified material that demonstrated enhanced adsorption of aniline, salicylaldehyde, benzyl alcohol, and xylene relative to that obtained from a combination of polyurethane foam and XAD-2 resin. The adsorption efficiency of benzyl alcohol by these aryl glass fibers was found to be as high as 93% and the adsorption mechanism is believed to be associated with hydrogen bonding and pi-pi conjugation. This study provides a reliable technique for the quantification of VBSCs and a basis for the evaluation of various adsorption materials. |
WOS研究方向 | Environmental Sciences |
源URL | [http://ir.rcees.ac.cn/handle/311016/45649] ![]() |
专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
作者单位 | 1.Jianghan Univ, Inst Environm & Hlth, Hubei Key Lab Environm & Hlth Effects Persistent, Wuhan 430056, Peoples R China 2.Chinese Acad Sci, State Key Lab Environm Chem & Ecotoxicol, Res Ctr Ecoenvironm Sci, Beijing 100085, Peoples R China 3.Jianghan Univ, Inst Interdisciplinary Res, Wuhan 430056, Peoples R China 4.Nanjing Forestry Univ, Coinnovat Ctr Efficient Proc & Utilizat Forest Re, Nanjing 210037, Peoples R China |
推荐引用方式 GB/T 7714 | Guo, Rui,Jiang, Sijing,Hu, Ming,et al. Adsorption of volatile benzene series compounds by surface-modified glass fibers: kinetics, thermodynamic adsorption efficiencies, and mechanisms[J]. ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,2021,28(24):30898-30907. |
APA | Guo, Rui,Jiang, Sijing,Hu, Ming,Zhan, Yuhang,Cheng, Kun,&Duan, Gaigai.(2021).Adsorption of volatile benzene series compounds by surface-modified glass fibers: kinetics, thermodynamic adsorption efficiencies, and mechanisms.ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,28(24),30898-30907. |
MLA | Guo, Rui,et al."Adsorption of volatile benzene series compounds by surface-modified glass fibers: kinetics, thermodynamic adsorption efficiencies, and mechanisms".ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH 28.24(2021):30898-30907. |
入库方式: OAI收割
来源:生态环境研究中心
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