Oxidative transformation of 1-naphthylamine in water mediated by different environmental black carbons
文献类型：期刊论文
| 作者 | Yang, Yanting; Pei, Zhiguo ; Yan, Liangguo; Ma, Jie; Zhang, Ziyu; Li, Yingming; Yang, Ruiqiang; Wang, Pu; Zhu, Ying; Zhang, Qinghua
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| 刊名 | JOURNAL OF HAZARDOUS MATERIALS
 |
| 出版日期 | 2021-02-05 |
| 卷号 | 403页码:- |
| 关键词 | Black carbon 1-Naphthylamine Mediation Oxidation Reactive oxygen species |
| ISSN号 | 0304-3894 |
| 英文摘要 | Black carbons (BCs) are ubiquitous in the natural environment and can significantly influence the environmental behavior of pollutants. This work examined the mediating effects of graphite, soot, and biochar on 1-naphthylamine (1-NA) oxidation under aerobic conditions. It was shown that the three BCs significantly promoted the oxidation of 1-NA in the dark, and the mediation efficiency of graphite was much greater than that of soot or biochar. The oxidation products were the coupling oligomers (dimers and trimers) and the oxygen-containing oligomers of 1-NA (di-OH-1-NA, OH-azo naphthalene, OH-trimers and amino-naphthoquinone derivatives etc.). The phenolic -OH on BCs were identified as the active sites for 1-NA oxidation, which could stimulate O-2 to produce reactive oxygen species through successive single electron transfer and then cause 1-NA oxidation. Moreover, the superior catalytic performance of graphite was also related to its high electrical conductivity. The synergies between the sp(2)-hybridized carbon surface and the active sites (such as phenolic -OH and defects) facilitated the oxidation of 1-NA on graphite. Findings in this study not only are helpful for better understanding the reactivity of environmental BCs, but also provide new insights into the risk assessment of 1-NA in the natural environment. |
| WOS研究方向 | Engineering, Environmental ; Environmental Sciences |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/45802]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, POB 2871, Beijing 100085, Peoples R China 2.Jinan Univ, Sch Water Conservancy & Environm, Jinan 250022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Yanting,Pei, Zhiguo,Yan, Liangguo,et al. Oxidative transformation of 1-naphthylamine in water mediated by different environmental black carbons[J]. JOURNAL OF HAZARDOUS MATERIALS,2021,403:-. |
| APA | Yang, Yanting.,Pei, Zhiguo.,Yan, Liangguo.,Ma, Jie.,Zhang, Ziyu.,...&Zhang, Qinghua.(2021).Oxidative transformation of 1-naphthylamine in water mediated by different environmental black carbons.JOURNAL OF HAZARDOUS MATERIALS,403,-. |
| MLA | Yang, Yanting,et al."Oxidative transformation of 1-naphthylamine in water mediated by different environmental black carbons".JOURNAL OF HAZARDOUS MATERIALS 403(2021):-. |
入库方式： OAI收割
来源：生态环境研究中心
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