中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Recognition and Prioritization of Chemical Mixtures and Transformation Products in Chinese Estuarine Waters by Suspect Screening Analysis

文献类型:期刊论文

作者Feng, Xiaoxia; Li, Dong; Liang, Wenqing; Ruan, Ting; Jiang, Guibin
刊名ENVIRONMENTAL SCIENCE & TECHNOLOGY
出版日期2021-07-20
卷号55期号:14页码:9508-9517
关键词nontargeted analysis chemical prioritization ToxCast estuarine transformation products
ISSN号0013-936X
英文摘要Chemical mixtures in surface waters could have significant impacts on exposure risks to human beings and pollution stress to aquatic system. By suspect screening analysis of high-resolution mass spectrometry data, occurrence, and compositions of ToxCast chemicals were investigated in grab estuarine water samples from a combination of 20 rivers that represents approximately 70% of the total river flow discharge along the east coast of China. In total, 59 ToxCast chemicals in seven use categories were identified, in which pesticides, intermediates, and pharmaceuticals were the abundant analogues. Significant differences in pollutant composition profiles were noticed, which possibly reflected singular release pattern and geographical-relevant usage preference (especially for herbicides and fungicides in the pesticide category). With the aid of tentative quantitative/semiquantitative measurement, essential contributors to the cumulative pollutant mass discharges and aquatic acute toxicity potentials were focused onto few particular chemicals. Existence of transformation products was further explored, which indicated that the fates of the selected parent ToxCast chemicals could be influenced by dominating transformation reactions (e.g., N-dealkylation and hydroxylation) and possible environmental factors (i.e., microbial activity). The results emphasize the necessity of suspect screening analysis for assessing the influence of terrestrial emissions of pollutants to the surrounding environment.
WOS研究方向Engineering, Environmental ; Environmental Sciences
源URL[http://ir.rcees.ac.cn/handle/311016/45825]  
专题生态环境研究中心_环境化学与生态毒理学国家重点实验室
作者单位1.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Feng, Xiaoxia,Li, Dong,Liang, Wenqing,et al. Recognition and Prioritization of Chemical Mixtures and Transformation Products in Chinese Estuarine Waters by Suspect Screening Analysis[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2021,55(14):9508-9517.
APA Feng, Xiaoxia,Li, Dong,Liang, Wenqing,Ruan, Ting,&Jiang, Guibin.(2021).Recognition and Prioritization of Chemical Mixtures and Transformation Products in Chinese Estuarine Waters by Suspect Screening Analysis.ENVIRONMENTAL SCIENCE & TECHNOLOGY,55(14),9508-9517.
MLA Feng, Xiaoxia,et al."Recognition and Prioritization of Chemical Mixtures and Transformation Products in Chinese Estuarine Waters by Suspect Screening Analysis".ENVIRONMENTAL SCIENCE & TECHNOLOGY 55.14(2021):9508-9517.

入库方式: OAI收割

来源:生态环境研究中心

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