Stabilizing Black Phosphorus via Covalent Functionalization of Solvent Formamide
文献类型：期刊论文
| 作者 | He, Zuoliang; Liu, Rui; Shan, Wanyu; Zhao, Huachao; Lai, Yujian; Li, Peng; Liu, Jingfu |
| 刊名 | ADVANCED MATERIALS INTERFACES
 |
| 出版日期 | 2021-06 |
| 卷号 | 8期号:11页码:- |
| 关键词 | black phosphorus covalent functionalization formamide stability enhancement |
| ISSN号 | 2196-7350 |
| 英文摘要 | Black phosphorus (BP) has been attracting increasing scientific and technological interest for its excellent materials properties, but suffers from the intrinsic easy oxidization due to the high reactivity of lone-pair electrons in each phosphorus atom. Herein, solvent formamide (FM) is proposed for the covalent modification of BP by a one-step ultrasonication without any additive. FM is demonstrated to functionalize BP by the formation of single covalent bond P-N, thus occupying the active lone-pair electrons of P atoms and leading to the significant enhancement of the antioxidative capacity of BP. Density functional theory calculations also rationalize the formation of stable P-N bond and its contribution to the high solvent-exfoliated efficiency during the exfoliation of BP. The plausible reaction mechanism of FM with BP and the final 5-membered ring structure of products are also proposed to explain the formation process of the stable P-N bonds. |
| WOS研究方向 | Chemistry, Multidisciplinary ; Materials Science, Multidisciplinary |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/45844]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 作者单位 | 1.Univ Chinese Acad Sci, Coll Resources & Environm, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China 3.Univ Chinese Acad Sci, Hangzhou Inst Adv Study, Sch Environm, Hangzhou 310024, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, Zuoliang,Liu, Rui,Shan, Wanyu,et al. Stabilizing Black Phosphorus via Covalent Functionalization of Solvent Formamide[J]. ADVANCED MATERIALS INTERFACES,2021,8(11):-. |
| APA | He, Zuoliang.,Liu, Rui.,Shan, Wanyu.,Zhao, Huachao.,Lai, Yujian.,...&Liu, Jingfu.(2021).Stabilizing Black Phosphorus via Covalent Functionalization of Solvent Formamide.ADVANCED MATERIALS INTERFACES,8(11),-. |
| MLA | He, Zuoliang,et al."Stabilizing Black Phosphorus via Covalent Functionalization of Solvent Formamide".ADVANCED MATERIALS INTERFACES 8.11(2021):-. |
入库方式： OAI收割
来源：生态环境研究中心
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