Constructing chemical stable 4-carboxyl-quinoline linked covalent organic frameworks via Doebner reaction for nanofiltration
文献类型：期刊论文
| 作者 | Yang, Yongliang; Yu, Ling; Chu, Tiancheng; Niu, Hongyun ; Wang, Jun; Cai, Yaqi
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| 刊名 | NATURE COMMUNICATIONS
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| 出版日期 | 2022-05-12 |
| 卷号 | 13期号:1页码:2615 |
| 英文摘要 | Covalent linkages are the key component of covalent organic frameworks (COFs) and the development of stable and functional linkages is essential to broaden their application prospects. Here, the authors report the synthesis of crystalline and ultrastable 4-carboxyl-quinoline linked COFs via Doebner reactions in both one-pot and post-synthetic modification methods and demonstrate application of the COFs in nanofiltration. Covalent linkages are the key component of covalent organic frameworks (COFs). The development of stable and functional linkages is essential to expand the COFs family and broaden their application prospects. In this work, we report the synthesis of crystalline and chemical stable 4-carboxyl-quinoline linked COFs (QL-COFs) via Doebner reactions in both one-pot (OP) and post-synthetic modification (PSM) methods. Both methods can be universally applied to most of the reported imine COFs family via bottom-up construction or linkage conversion. Owing to the contractive pore size, more hydrophilic structure and better chemical stability than the conventional imine COFs endowed by 4-carboxyl-quinoline linkage, QL-COFs are supposed to possess a wider application range. We further demonstrate the nanofiltration membrane (NFM) based on QL-COF exhibited a desirable separation capacity with high rejection for small dye molecules (> 90%), high water permeance (850 L m(-2) h(-1) MPa-1) and tolerance of extreme conditions (1 M HCl/NaOH), which were benefitted from the enhanced properties of QL-COFs. Additionally, efficient ion sieving properties were also achieved by QL-COF membrane. We anticipate that this work opens up a way for the construction of robust and functional COFs materials for practical applications. |
| 源URL | [https://ir.rcees.ac.cn/handle/311016/47492]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Natl Engn Res Ctr Ind Wastewater Detoxicat & Reso, Res Ctr Ecoenvironm Sci, B 2.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Aquat Chem, Beijing 100085, Peoples R China 3.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China 4.Zhejiang Univ Technol, Ctr Membrane Arid Water Sci & Technol, State Key Lab Breeding Base Green Chem Synth Tech, Inst Ocean & Environm Chem Engn, Hangzhou 310014, Peoples R China 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Yongliang,Yu, Ling,Chu, Tiancheng,et al. Constructing chemical stable 4-carboxyl-quinoline linked covalent organic frameworks via Doebner reaction for nanofiltration[J]. NATURE COMMUNICATIONS,2022,13(1):2615. |
| APA | Yang, Yongliang,Yu, Ling,Chu, Tiancheng,Niu, Hongyun,Wang, Jun,&Cai, Yaqi.(2022).Constructing chemical stable 4-carboxyl-quinoline linked covalent organic frameworks via Doebner reaction for nanofiltration.NATURE COMMUNICATIONS,13(1),2615. |
| MLA | Yang, Yongliang,et al."Constructing chemical stable 4-carboxyl-quinoline linked covalent organic frameworks via Doebner reaction for nanofiltration".NATURE COMMUNICATIONS 13.1(2022):2615. |
入库方式： OAI收割
来源：生态环境研究中心
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