中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Design, synthesis, and evaluation of a highly effective and safe perfluoro-alternative with a weak site: potassium 1,1,2,2,3,3,4,4-octafluoro-4-(perfluorobutoxy)butane-1-sulfonate

文献类型:期刊论文

作者Guo, Rui; Gao, Yangguang; Liu, Guoxing
刊名GREEN CHEMISTRY
出版日期2022-02-07
卷号24期号:3页码:1114-1119
关键词POLYFLUOROALKYL SUBSTANCES PFOS DEGRADATION TOXICITY
ISSN号1463-9262
英文摘要A novel, highly efficient, degradable alternative perfluorinated compound (APFC) with a weak site was synthesized using various methods via a common intermediate. The main reactions were oxidation by sulfonyl chloride, chlorination, and electrolytic fluorination. The synthetic strategies were efficient and suitable for industrial production of the APFC at the kilogram scale. The surface tension of the APFC and inhibition of chromium mist by the APFC were assessed. The APFC met the requirements for being produced industrially and also performed excellently, was resistant to degradation, and was shown to be more environmentally friendly than perfluorooctylsulfonic acid.
源URL[https://ir.rcees.ac.cn/handle/311016/47504]  
专题生态环境研究中心_环境化学与生态毒理学国家重点实验室
通讯作者Guo, Rui
作者单位1.Jianghan Univ, Inst Interdisciplinary Res, Wuhan 430056, Peoples R China
2.Jianghan Univ, Inst Environm & Hlth, Hubei Key Lab Environm & Hlth Effects Persistent, Wuhan 430056, Peoples R China
3.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China
4.Henan Agr Univ, Coll Sci, Zhengzhou 450001, Henan, Peoples R China
推荐引用方式
GB/T 7714
Guo, Rui,Gao, Yangguang,Liu, Guoxing. Design, synthesis, and evaluation of a highly effective and safe perfluoro-alternative with a weak site: potassium 1,1,2,2,3,3,4,4-octafluoro-4-(perfluorobutoxy)butane-1-sulfonate[J]. GREEN CHEMISTRY,2022,24(3):1114-1119.
APA Guo, Rui,Gao, Yangguang,&Liu, Guoxing.(2022).Design, synthesis, and evaluation of a highly effective and safe perfluoro-alternative with a weak site: potassium 1,1,2,2,3,3,4,4-octafluoro-4-(perfluorobutoxy)butane-1-sulfonate.GREEN CHEMISTRY,24(3),1114-1119.
MLA Guo, Rui,et al."Design, synthesis, and evaluation of a highly effective and safe perfluoro-alternative with a weak site: potassium 1,1,2,2,3,3,4,4-octafluoro-4-(perfluorobutoxy)butane-1-sulfonate".GREEN CHEMISTRY 24.3(2022):1114-1119.

入库方式: OAI收割

来源:生态环境研究中心

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