Size-dependent flame retardancy of black phosphorus nanosheets
文献类型：期刊论文
| 作者 | Duan, Zunbin; Wang, Yanfang; Bian, Shi; Liu, Danni; Zhang, Yanli; Zhang, Xue; He, Rui; Wang, Jiahong; Qu, Guangbo ; Chu, Paul K.
|
| 刊名 | NANOSCALE
 |
| 出版日期 | 2022-02-17 |
| 卷号 | 14期号:7页码:2599-2604 |
| 关键词 | NANOPARTICLE GEOMETRY RAMAN-SPECTROSCOPY NANOCOMPOSITES EXFOLIATION GRAPHITE SURFACE |
| ISSN号 | 2040-3364 |
| 英文摘要 | Two-dimensional black phosphorus (BP) nanosheets are potential flame-retardant nano-additives. Herein, the effects of the size of BP nanosheets embedded in epoxy resin (EP) on flame retardancy are studied. BP nanosheets with four different sizes are synthesized from bulk BP by different exfoliation methods including solid ball milling, liquid ball milling, ultrasonic liquid exfoliation, and electrochemical exfoliation (samples are designated as sb-BP, lb-BP, us-BP, and ec-BP, respectively). lb-BP exhibits the best dispersion in the EP matrix, and the lb-BP/EP composite shows the best flame-retardancy properties among the four BP/EP composites. Compared to bare EP, lb-BP/EP shows obvious improvements including the reduction in the heat release peak rate by 34.4%, total heat release by 27.0%, peak of smoke production rate by 69.2%, and total production of carbon monoxide by 50.8%. The mechanistic study reveals that lb-BP serves as a barrier and carbonization catalyst to delay combustion. These results confirm the size dependence of flame-retardancy properties of BP nanosheets and the new knowledge provides insights into the size dependent effects of other two-dimensional materials. |
| 源URL | [https://ir.rcees.ac.cn/handle/311016/47617]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 作者单位 | 1.Northeast Forestry Univ, Coll Chem Chem Engn & Resource Utilizat, Heilongjiang Key Lab Mol Design & Preparat Flame, Harbin 150040, Peoples R China 2.Chinese Acad Sci, Shenzhen Engn Ctr Fabricat Two Dimens Atom Crysta, Shenzhen Inst Adv Technol, Shenzhen 518055, Peoples R China 3.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China 4.City Univ Hong Kong, Dept Phys, Dept Mat Sci & Engn, Dept Biomed Engn, Tat Chee Ave, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Duan, Zunbin,Wang, Yanfang,Bian, Shi,et al. Size-dependent flame retardancy of black phosphorus nanosheets[J]. NANOSCALE,2022,14(7):2599-2604. |
| APA | Duan, Zunbin.,Wang, Yanfang.,Bian, Shi.,Liu, Danni.,Zhang, Yanli.,...&Yu, Xue-Feng.(2022).Size-dependent flame retardancy of black phosphorus nanosheets.NANOSCALE,14(7),2599-2604. |
| MLA | Duan, Zunbin,et al."Size-dependent flame retardancy of black phosphorus nanosheets".NANOSCALE 14.7(2022):2599-2604. |
入库方式： OAI收割
来源：生态环境研究中心
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