The bimetallic effect promotes the activity of Rh in catalyzed selective hydrogenation of phenol
文献类型：期刊论文
| 作者 | Li, Shiwei ; Zhao, Huachao; Ran, Wei; Liu, Jingfu; Liu, Rui
|
| 刊名 | CHEMICAL COMMUNICATIONS
 |
| 出版日期 | 2022-09-15 |
| 卷号 | 58期号:74页码:10357-10360 |
| 关键词 | GOLD |
| ISSN号 | 1359-7345 |
| 英文摘要 | Au@RhPd ultrathin nanowires are designed as a highly reactive and selective catalyst for the hydrogenation of phenol under ambient conditions. Au NWs modulate the electronic state of Rh atoms to enhance the adsorption of phenol and desorption of cyclohexanone. Pd works as a cocatalyst to activate H-2 to H* and spillover to Rh sites. This new catalyst shows a turnover frequency of up to 560 h(-1) for a wide spectrum of phenols with >80% selectivity toward cyclohexanones. |
| 源URL | [https://ir.rcees.ac.cn/handle/311016/47628]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 通讯作者 | Liu, Rui |
| 作者单位 | 1.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China 2.Univ Chinese Acad Sci, Coll Resources & Environm, Beijing 100049, Peoples R China 3.UCAS, Hangzhou Inst Adv Study, Sch Environm, Hangzhou 310024, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Shiwei,Zhao, Huachao,Ran, Wei,et al. The bimetallic effect promotes the activity of Rh in catalyzed selective hydrogenation of phenol[J]. CHEMICAL COMMUNICATIONS,2022,58(74):10357-10360. |
| APA | Li, Shiwei,Zhao, Huachao,Ran, Wei,Liu, Jingfu,&Liu, Rui.(2022).The bimetallic effect promotes the activity of Rh in catalyzed selective hydrogenation of phenol.CHEMICAL COMMUNICATIONS,58(74),10357-10360. |
| MLA | Li, Shiwei,et al."The bimetallic effect promotes the activity of Rh in catalyzed selective hydrogenation of phenol".CHEMICAL COMMUNICATIONS 58.74(2022):10357-10360. |
入库方式： OAI收割
来源：生态环境研究中心
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