Total Organic Carbon as a Quantitative Index of Micro- and Nano-Plastic Pollution
文献类型:期刊论文
作者 | Li, Peng![]() ![]() ![]() ![]() ![]() ![]() |
刊名 | ANALYTICAL CHEMISTRY
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出版日期 | 2022-01-18 |
卷号 | 94期号:2页码:740-747 |
关键词 | BLACK CARBON ENVIRONMENTAL-SAMPLES MICROPLASTICS QUANTIFICATION IDENTIFICATION WASTE POLYETHYLENE BIOCHAR |
ISSN号 | 0003-2700 |
英文摘要 | The global pollution of micro- and nano-plastics (MNPs) calls for monitoring methods. As diverse mixtures of various sizes, morphologies, and chemical compositions in the environment, MNPs are currently quantified based on mass or number concentrations. Here, we show total organic carbon (TOC) as an index for quantifying the pollution of total MNPs in environmental waters. Two parallel water samples are respectively filtered with a carbon-free glass fiber membrane. Then, one membrane with the collected particulate substances is treated by potassium peroxodisulfate oxidation and Fenton digestion in sequence for quantifying the sum of MNPs and particulate black carbon (PBC) as TOCMNP&PBC using a TOC analyzer, another membrane is treated by sulfonation and Fenton digestion for quantifying PBC as TOCPBC, and the TOC of MNPs is calculated by subtracting TOCPBC from TOCMNP&PBC. The feasibility of our method is demonstrated by determination of various MNPs of representative plastic types and sizes (0.5-100 mu m) in tap, river, and sea water samples, with low detection limits (similar to 7 mu g C L-1) and high spiked recoveries (83.7-114%). TOC is a powerful index for routine monitoring of MNP pollution. |
源URL | [https://ir.rcees.ac.cn/handle/311016/47634] ![]() |
专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
通讯作者 | Liu, Jingfu |
作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China 3.Texas A&M Univ, Sch Publ Hlth, Dept Environm & Occupat Hlth, College Stn, TX 77843 USA 4.Georgia Inst Technol, Sch Civil & Environm Engn, Atlanta, GA 30332 USA 5.UCAS, Hangzhou Inst Adv Study, Sch Environm, Hangzhou 310024, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Peng,Lai, Yujian,Li, Qingcun,et al. Total Organic Carbon as a Quantitative Index of Micro- and Nano-Plastic Pollution[J]. ANALYTICAL CHEMISTRY,2022,94(2):740-747. |
APA | Li, Peng.,Lai, Yujian.,Li, Qingcun.,Dong, Lijie.,Tan, Zhiqiang.,...&Jiang, Guibin.(2022).Total Organic Carbon as a Quantitative Index of Micro- and Nano-Plastic Pollution.ANALYTICAL CHEMISTRY,94(2),740-747. |
MLA | Li, Peng,et al."Total Organic Carbon as a Quantitative Index of Micro- and Nano-Plastic Pollution".ANALYTICAL CHEMISTRY 94.2(2022):740-747. |
入库方式: OAI收割
来源:生态环境研究中心
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