Vital Environmental Sources for Multitudinous Fluorinated Chemicals: New Evidence from Industrial Byproducts in Multienvironmental Matrices in a Fluorochemical Manufactory
文献类型：期刊论文
| 作者 | He, Anen ; Liang, Yong; Li, Feifei; Lu, Yao; Liu, Chao; Li, Juan; Zhou, Zhen; Zhu, Nali; Liao, Chunyang; Wang, Yawei
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| 刊名 | ENVIRONMENTAL SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2022 |
| 卷号 | 56期号:23页码:1-12 |
| ISSN号 | 0013-936X |
| 关键词 | per- and polyfluoroalkyl substances (PFASs) fluorochemical plant electrochemical fluorination industrial byproducts environmental source |
| 英文摘要 | Direct emissions from fluorochemical manufactory are an important source of per- and polyfluoroalkyl substances (PFASs) to the environment. In this study, a wide range of PFASs, including 8 legacy PFASs, 8 long-chain perfluoroalkyl carboxylic acids (PFCAs), and 40 emerging PFASs, were investigated through a target screening in multienvironmental matrices from a fluorochemical manufactory in China. Indoor dust was the most polluted matrix, wherein 52 PFASs were detected, and the median concentration of long-chain PFCA was 276 ng/g. A high level of short-chain PFAS in total suspended particles (median concentration = 416 ng/m(3)) and the effluent in the manufactory (Sigma(48)PFAS = 212 mu g/L) will undoubtedly increase the burden on the surrounding environment. Twenty-four industrial byproducts were ascertained to be generated during the electrochemical fluorination (ECF) process, and eight fluorinated alternatives were considered to be produced during product development. Twelve PFASs were quantified for the first time in the working environments. Perfluoropropane sulfonic acid, perfluoro (2-ethoxyethane) sulfonic acid (PFEESA), and 2-perfluorohexyl ethanoic acid are abundant fluorinated alternatives, with median levels of 118717204 ng/g in the dust. Significant positive correlations between ECF-related PFAS products and byproducts indicate that the detected values are strongly connected with the industrial source. Hierarchical cluster analysis further manifests their affiliation. Our findings raise the need for further investigations of emerging PFAS (including the first report of PFAS, such as PFEESA, in the environment) which may be released during the production process in the fluorochemical manufactories. |
| 源URL | [https://ir.rcees.ac.cn/handle/311016/48524]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 作者单位 | 1.University of Chinese Academy of Sciences, CAS 2.Chinese Academy of Sciences 3.Research Center for Eco-Environmental Sciences (RCEES) 4.Jianghan University |
| 推荐引用方式 GB/T 7714 | He, Anen,Liang, Yong,Li, Feifei,et al. Vital Environmental Sources for Multitudinous Fluorinated Chemicals: New Evidence from Industrial Byproducts in Multienvironmental Matrices in a Fluorochemical Manufactory[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2022,56(23):1-12. |
| APA | He, Anen.,Liang, Yong.,Li, Feifei.,Lu, Yao.,Liu, Chao.,...&Jiang, Guibin.(2022).Vital Environmental Sources for Multitudinous Fluorinated Chemicals: New Evidence from Industrial Byproducts in Multienvironmental Matrices in a Fluorochemical Manufactory.ENVIRONMENTAL SCIENCE & TECHNOLOGY,56(23),1-12. |
| MLA | He, Anen,et al."Vital Environmental Sources for Multitudinous Fluorinated Chemicals: New Evidence from Industrial Byproducts in Multienvironmental Matrices in a Fluorochemical Manufactory".ENVIRONMENTAL SCIENCE & TECHNOLOGY 56.23(2022):1-12. |
入库方式： OAI收割
来源：生态环境研究中心
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