Self-Assembled Hierarchical CuxO@C18H36O2 Nanoflakes for Superior Fenton-like Catalysis over a Wide Range of pH
文献类型：期刊论文
| 作者 | Rehman, Ratul; Lahiri, Sudip Kumar; Islam, Ashraful; Wei, Peng; Xu, Yue |
| 刊名 | ACS OMEGA
 |
| 出版日期 | 2021-08-31 |
| 卷号 | 6期号:34页码:22188-22201 |
| ISSN号 | 2470-1343 |
| 英文摘要 | A novel copper-based catalyst supported by a long-chain hydrocarbon stearic acid (CuxO@C18H36O2) was synthesized by a hydrothermal method and double replacement reactions. The as-prepared catalyst is shown as self-assembled hierarchical nanoflakes with an average size of similar to 22 nm and a specific surface area of 51.4 m(2) g(-1). The catalyst has a good performance on adsorption as well as Fenton-like catalytic degradation of Rhodamine B (RhB). The catalyst (10 mg/L) showed an excellent adsorption efficiency toward RhB (20 mg/L) for pH ranging from 5 to 13, with the highest adsorption rate (99%) exhibited at pH 13. The Fenton-like catalytic degradation reaction of RhB (20 mg/L) by CuxO@C18H36O2 nanoflakes was effective over a wide range of pH of 3-11, and (OH)-O-center dot radicals were generated via Cu2O/H2O2 interactions in acidic conditions and CuO/H2O2 reactions in a neutral solution. The highest efficiency catalytic degradation of RhB (20 mg/L) was 99.2% under acidic conditions (pH = 3, H2O2 = 0.05 M), with an excellent reusability of 96% at the 6th cycle. The results demonstrated that the as-prepared CuxO@C18H36O2 nanoflakes are an efficient candidate for wastewater treatment, with excellent adsorption capacity and superior Fenton-like catalytic efficiency and stability for RhB. |
| WOS研究方向 | Chemistry, Multidisciplinary |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/45997]  |
| 专题 | 生态环境研究中心_环境水质学国家重点实验室 |
| 作者单位 | 1.Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, Wuhan 430074, Peoples R China 2.Huazhong Univ Sci & Technol, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Peoples R China 3.Chinese Acad Sci, Univ Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Aquat Chem, Beijing 100085, Peoples R China |
| 推荐引用方式 GB/T 7714 | Rehman, Ratul,Lahiri, Sudip Kumar,Islam, Ashraful,et al. Self-Assembled Hierarchical CuxO@C18H36O2 Nanoflakes for Superior Fenton-like Catalysis over a Wide Range of pH[J]. ACS OMEGA,2021,6(34):22188-22201. |
| APA | Rehman, Ratul,Lahiri, Sudip Kumar,Islam, Ashraful,Wei, Peng,&Xu, Yue.(2021).Self-Assembled Hierarchical CuxO@C18H36O2 Nanoflakes for Superior Fenton-like Catalysis over a Wide Range of pH.ACS OMEGA,6(34),22188-22201. |
| MLA | Rehman, Ratul,et al."Self-Assembled Hierarchical CuxO@C18H36O2 Nanoflakes for Superior Fenton-like Catalysis over a Wide Range of pH".ACS OMEGA 6.34(2021):22188-22201. |
入库方式： OAI收割
来源：生态环境研究中心
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。