The Sustainable Development Path of the Gold Exploration and Mining of the Sanshan Island-Jiaojia Belt in Laizhou Bay: A DID-SVAR Approach
文献类型:期刊论文
作者 | Zhang, Sheng; Han, Guoxiang; Yu, Ran; Wen, Zuhui; Xu, Meng; Yang, Yifu |
刊名 | SUSTAINABILITY
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出版日期 | 2021 |
卷号 | 42期号:6页码:328-334 |
ISSN号 | 0195-5373 |
英文摘要 | The method of isotope dilution and tracing, based on ethylation-purge and trap-gas chromatography (GC)-inductively coupled plasma mass spectrometry (ICP-MS), has been widely used for the accurate analysis of methylmercury (MeHg) and for tracking its environmental fates (e.g., formation/degradation). However, the tedious ethylation derivatization and purge and trap processes limit analytical throughput. In this work, an automatic ethylation derivatization and purge and trap method, followed by GC separation, pyrolysis, and ICP-MS detection, was developed for MeHg analysis. The throughput and detection limits of this proposed method for MeHg were 7.5 min/sample and 0.03 ng L-1, respectively, with a relative standard deviation of 3.7%. The accuracy of the developed method was validated by the analysis of a spiked water sample and a certified reference material (DORM-4, Fish protein) using isotope dilution ((MeHg)-Hg-201). In addition, anaerobic Geobacter sulfurreducens PCA-mediated methylation of He2+ and demethylation of MeHg was monitored by using double-enriched isotope tracing (He-199(2+) and (MeHg)-Hg-201). This automatic ethylation-purge and trap-GC-ICP-MS method is promising for routine MeHg analysis with isotope dilution/tracing. |
源URL | [https://ir.rcees.ac.cn/handle/311016/46768] ![]() |
专题 | 生态环境研究中心_城市与区域生态国家重点实验室 |
作者单位 | 1.Beijing Jiaotong Univ, Sch Sci, Dept Math, Beijing 100044, Peoples R China 2.Renmin Univ China, Sch Environm & Nat Resources, Beijing 100872, Peoples R China 3.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Urban & Reg Ecol, Beijing 100085, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Sheng,Han, Guoxiang,Yu, Ran,et al. The Sustainable Development Path of the Gold Exploration and Mining of the Sanshan Island-Jiaojia Belt in Laizhou Bay: A DID-SVAR Approach[J]. SUSTAINABILITY,2021,42(6):328-334. |
APA | Zhang, Sheng,Han, Guoxiang,Yu, Ran,Wen, Zuhui,Xu, Meng,&Yang, Yifu.(2021).The Sustainable Development Path of the Gold Exploration and Mining of the Sanshan Island-Jiaojia Belt in Laizhou Bay: A DID-SVAR Approach.SUSTAINABILITY,42(6),328-334. |
MLA | Zhang, Sheng,et al."The Sustainable Development Path of the Gold Exploration and Mining of the Sanshan Island-Jiaojia Belt in Laizhou Bay: A DID-SVAR Approach".SUSTAINABILITY 42.6(2021):328-334. |
入库方式: OAI收割
来源:生态环境研究中心
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