中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
The Sustainable Development Path of the Gold Exploration and Mining of the Sanshan Island-Jiaojia Belt in Laizhou Bay: A DID-SVAR Approach

文献类型:期刊论文

作者Zhang, Sheng; Han, Guoxiang; Yu, Ran; Wen, Zuhui; Xu, Meng; Yang, Yifu
刊名SUSTAINABILITY
出版日期2021
卷号42期号:6页码:328-334
ISSN号0195-5373
英文摘要The method of isotope dilution and tracing, based on ethylation-purge and trap-gas chromatography (GC)-inductively coupled plasma mass spectrometry (ICP-MS), has been widely used for the accurate analysis of methylmercury (MeHg) and for tracking its environmental fates (e.g., formation/degradation). However, the tedious ethylation derivatization and purge and trap processes limit analytical throughput. In this work, an automatic ethylation derivatization and purge and trap method, followed by GC separation, pyrolysis, and ICP-MS detection, was developed for MeHg analysis. The throughput and detection limits of this proposed method for MeHg were 7.5 min/sample and 0.03 ng L-1, respectively, with a relative standard deviation of 3.7%. The accuracy of the developed method was validated by the analysis of a spiked water sample and a certified reference material (DORM-4, Fish protein) using isotope dilution ((MeHg)-Hg-201). In addition, anaerobic Geobacter sulfurreducens PCA-mediated methylation of He2+ and demethylation of MeHg was monitored by using double-enriched isotope tracing (He-199(2+) and (MeHg)-Hg-201). This automatic ethylation-purge and trap-GC-ICP-MS method is promising for routine MeHg analysis with isotope dilution/tracing.
源URL[https://ir.rcees.ac.cn/handle/311016/46768]  
专题生态环境研究中心_城市与区域生态国家重点实验室
作者单位1.Beijing Jiaotong Univ, Sch Sci, Dept Math, Beijing 100044, Peoples R China
2.Renmin Univ China, Sch Environm & Nat Resources, Beijing 100872, Peoples R China
3.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Urban & Reg Ecol, Beijing 100085, Peoples R China
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GB/T 7714
Zhang, Sheng,Han, Guoxiang,Yu, Ran,et al. The Sustainable Development Path of the Gold Exploration and Mining of the Sanshan Island-Jiaojia Belt in Laizhou Bay: A DID-SVAR Approach[J]. SUSTAINABILITY,2021,42(6):328-334.
APA Zhang, Sheng,Han, Guoxiang,Yu, Ran,Wen, Zuhui,Xu, Meng,&Yang, Yifu.(2021).The Sustainable Development Path of the Gold Exploration and Mining of the Sanshan Island-Jiaojia Belt in Laizhou Bay: A DID-SVAR Approach.SUSTAINABILITY,42(6),328-334.
MLA Zhang, Sheng,et al."The Sustainable Development Path of the Gold Exploration and Mining of the Sanshan Island-Jiaojia Belt in Laizhou Bay: A DID-SVAR Approach".SUSTAINABILITY 42.6(2021):328-334.

入库方式: OAI收割

来源:生态环境研究中心

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