N-nitration of secondary aliphatic amines in the particle phase
文献类型：期刊论文
| 作者 | Chen, Tianzeng ; Ge, Yanli; Liu, Yongchun; He, Hong
|
| 刊名 | CHEMOSPHERE
 |
| 出版日期 | 2022-04 |
| 卷号 | 293期号:0页码:133639 |
| 关键词 | AEROSOL FORMATION ORGANIC AEROSOL AMMONIUM-SALTS SULFURIC-ACID NITROSATION CAPTURE SPECTRA PH N,N-DIMETHYLFORMAMIDE TRIMETHYLAMINE |
| ISSN号 | 0045-6535 |
| 英文摘要 | Amines are frequently detected in atmospheric particles and are internally mixed with other particle-phase components. However, research on the further reactions of amine with reactive species after entering the particle phase is still limited. This study investigated the nitration reaction process of particulate dimethylamine (DMA), formed via a substitution reaction between DMA and (NH4)2SO4, with NOx. In situ attenuated total reflectance-infrared Fourier transform spectroscopy (in situ ATR-FTIR) and proton transfer reaction mass spectroscopy (PTR-MS), as well as DFT methods at the B3LYP level using the 6-311++G (d, p) basis set, were mainly used to confirm the formation of nitramine and nitrosamine in the nitration/nitrosation process of DMA. A hydrogen-bonding intermediate ([(CH3)2NMIDLINE HORIZONTAL ELLIPSISHONO]) is initially formed when particulate DMA reacts with NO2 followed by aminyl radical formation, and then nitr- and nitros-amine form through addition reactions with NO2 and NO, respectively. The dimer of NO2 (i.e., N2O4) and the product of NO and NO2 (i.e., N2O3) can also react with DMA to attack the lone pair electrons on the central N atom of DMA to finally form nitr- and nitros-amine. This study helps reveal the nitration reaction mechanism of organic amines in the particle phase. It also aids in understanding the process of nitrogen cycling in the atmosphere. |
| 源URL | [https://ir.rcees.ac.cn/handle/311016/47417]  |
| 专题 | 生态环境研究中心_大气污染控制中心 |
| 作者单位 | 1.Beijing Univ Chem Technol, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, Aerosol & Haze Lab, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100085, Peoples R China 3.Peking Univ, Coll Environm Sci & Engn, State Key Joint Lab Environm Simulat & Pollut Con, BIC E 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Chinese Acad Sci, Inst Urban Environm, Ctr Excellence Reg Atmospher Environm, Xiamen 361021, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Tianzeng,Ge, Yanli,Liu, Yongchun,et al. N-nitration of secondary aliphatic amines in the particle phase[J]. CHEMOSPHERE,2022,293(0):133639. |
| APA | Chen, Tianzeng,Ge, Yanli,Liu, Yongchun,&He, Hong.(2022).N-nitration of secondary aliphatic amines in the particle phase.CHEMOSPHERE,293(0),133639. |
| MLA | Chen, Tianzeng,et al."N-nitration of secondary aliphatic amines in the particle phase".CHEMOSPHERE 293.0(2022):133639. |
入库方式： OAI收割
来源：生态环境研究中心
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