Interaction between noble metals (Pt, Pd, Rh, Ir, Ag) and defect-enriched TiO2 and its application in toluene and propene catalytic oxidation
文献类型：期刊论文
| 作者 | Lu, Yuqin; Deng, Hua; Pan, Tingting; Wang, Lian ; Zhang, Changbin; He, Hong
|
| 刊名 | APPLIED SURFACE SCIENCE
 |
| 出版日期 | 2022 |
| 卷号 | 606页码:154834-1-12 |
| 关键词 | Toluene Propene Catalytic combustion Supported noble metal catalyst DFT calculation |
| ISSN号 | 0169-4332 |
| 英文摘要 | The particle size, electronic state, as well as metal-support interaction of supported noble metal catalysts significantly influence their VOC oxidation performance. A series of noble metals (including Pt, Pd, Rh, Ir, and Ag) was successfully loaded on TiO2 modified by hydrogen reduction to scrutinize their effects on toluene and propene combustion. The prepared catalysts were characterized by SEM, TEM, BET, XRD, ESR, UV-vis, H2-TPR, XPS, in-situ DRIFTS, GC-MS and DFT calculations. It was interesting to note that all the noble metals could be well-dispersed on the low-surface-area TiO2 support and modulated its properties. The electron transfer ability and oxygen mobility of the as-prepared materials were enhanced via noble metal doping. Among them, the Pd/ TiO2 and Pt/TiO2 catalysts exhibited excellent catalytic performance by inducing local electron transfer from TiO2 to the noble metal NPs via the strong metal-support interaction. Experimental results and theoretical cal-culations revealed that the activation of toluene, propene and oxygen on suitable interfaces contributed to the good performance of the Pd and Pt catalysts. This work explored and elucidated the effects of electron-rich noble metal catalysts in enhancing the activation of ground-state oxygen. |
| 源URL | [https://ir.rcees.ac.cn/handle/311016/48455]  |
| 专题 | 生态环境研究中心_大气污染控制中心 |
| 作者单位 | 1.University of Chinese Academy of Sciences, CAS 2.Chinese Academy of Sciences 3.Institute of Urban Environment, CAS 4.Research Center for Eco-Environmental Sciences (RCEES) |
| 推荐引用方式 GB/T 7714 | Lu, Yuqin,Deng, Hua,Pan, Tingting,et al. Interaction between noble metals (Pt, Pd, Rh, Ir, Ag) and defect-enriched TiO2 and its application in toluene and propene catalytic oxidation[J]. APPLIED SURFACE SCIENCE,2022,606:154834-1-12. |
| APA | Lu, Yuqin,Deng, Hua,Pan, Tingting,Wang, Lian,Zhang, Changbin,&He, Hong.(2022).Interaction between noble metals (Pt, Pd, Rh, Ir, Ag) and defect-enriched TiO2 and its application in toluene and propene catalytic oxidation.APPLIED SURFACE SCIENCE,606,154834-1-12. |
| MLA | Lu, Yuqin,et al."Interaction between noble metals (Pt, Pd, Rh, Ir, Ag) and defect-enriched TiO2 and its application in toluene and propene catalytic oxidation".APPLIED SURFACE SCIENCE 606(2022):154834-1-12. |
入库方式： OAI收割
来源：生态环境研究中心
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