More octahedral Cu+ and surface acid sites in uniformly porous Cu-Al2O3 for enhanced Fenton catalytic performances
文献类型：期刊论文
| 作者 | Li, Lingfei; Hu, Chun; Zhang, Lili ; Shi, Baoyou
|
| 刊名 | JOURNAL OF HAZARDOUS MATERIALS
 |
| 出版日期 | 2021-03-15 |
| 卷号 | 406页码:- |
| 关键词 | Fenton-like Gaseous template Porous Cu-doped alumina Surface active sites Contaminant degradation |
| ISSN号 | 0304-3894 |
| 英文摘要 | Porous Cu-doped alumina (P-Cu-Al2O3) has been synthesized using ammonium chloride as a green gaseous template. The unique pore-forming agent endows the catalyst a large surface area and homogenous pore structure. According to the characterization results by multi-technologies, the highly dispersed framework Cu+/ Cu2+ was incorporated in octahedral sites with the formation of the Cu-O-Al bonds. Compared with bulk Cu doped Al2O3 (B-Cu-Al2O3), more surface acidic oxygen-containing groups and Lewis acid sites existed in P-CuAl2O3, resulting in the production of surface adsorbed (OH)-O-center dot, which is helpful for the removal of surface adsorbed organic intermediates. In addition, O-2 more easily participate in surface reaction to promote the (OH)-O-center dot generation in P-Cu-Al2O3 system than that in B-Cu-Al2O3. As a result, the representative endocrine disruptor bisphenol A can be more efficiently mineralized by P-Cu-Al2O3. This work provides a facile route to develop porous active heterogenous Fenton-like catalysts and a unique perspective to insight into the structure-activity relationship. |
| WOS研究方向 | Engineering, Environmental ; Environmental Sciences |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/46238]  |
| 专题 | 生态环境研究中心_中国科学院饮用水科学与技术重点实验室 |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, Key Lab Drinking Water Sci & Technol, Beijing 100085, Peoples R China 3.Guangzhou Univ, Minist Educ, Key Lab Water Qual & Conservat Pearl River Delta, Inst Environm Res Greater Bay, Guangzhou 510006, Peoples R |
| 推荐引用方式 GB/T 7714 | Li, Lingfei,Hu, Chun,Zhang, Lili,et al. More octahedral Cu+ and surface acid sites in uniformly porous Cu-Al2O3 for enhanced Fenton catalytic performances[J]. JOURNAL OF HAZARDOUS MATERIALS,2021,406:-. |
| APA | Li, Lingfei,Hu, Chun,Zhang, Lili,&Shi, Baoyou.(2021).More octahedral Cu+ and surface acid sites in uniformly porous Cu-Al2O3 for enhanced Fenton catalytic performances.JOURNAL OF HAZARDOUS MATERIALS,406,-. |
| MLA | Li, Lingfei,et al."More octahedral Cu+ and surface acid sites in uniformly porous Cu-Al2O3 for enhanced Fenton catalytic performances".JOURNAL OF HAZARDOUS MATERIALS 406(2021):-. |
入库方式： OAI收割
来源：生态环境研究中心
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