Intrinsic viscosity of polymers: From linear chains to dendrimers
文献类型：期刊论文
| 作者 | Lu YY ; Shi TF ; An LJ ; Wang ZG |
| 刊名 | epl
 |
| 出版日期 | 2012 |
| 卷号 | 97期号:6页码:文献号: 64003 |
| 关键词 | DILUTE-SOLUTION BIOLOGICAL MACROMOLECULES FRICTION COEFFICIENT POLYSTYRENE STAR DYNAMICS BEHAVIOR ARCHITECTURE MOLECULES MODEL |
| ISSN号 | 0295-5075 |
| 通讯作者 | lu yy |
| 中文摘要 | we present a simple theory for the intrinsic viscosity of polymers of arbitrary architectures, based on a partially permeable sphere model. the model introduces two phenomenological functions, the drainage function kappa(r) and the drag function xi(r), which are determined by the density profile, as a mean-field description of the multi-body, long-range and accumulated effects of the hydrodynamic interactions. by combining debye's theory for free draining polymer chains with einstein's theory for hard spheres, we arrive at a simple expression for the intrinsic viscosity. results from our theory show broad agreement in all the key features of the intrinsic viscosity with existing experimental results for polymers ranging from linear chain to branched polymers to dendrimers. copyright (c) epla, 2012 |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000301953300015 |
| 公开日期 | 2013-10-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48863]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lu YY,Shi TF,An LJ,et al. Intrinsic viscosity of polymers: From linear chains to dendrimers[J]. epl,2012,97(6):文献号: 64003. |
| APA | Lu YY,Shi TF,An LJ,&Wang ZG.(2012).Intrinsic viscosity of polymers: From linear chains to dendrimers.epl,97(6),文献号: 64003. |
| MLA | Lu YY,et al."Intrinsic viscosity of polymers: From linear chains to dendrimers".epl 97.6(2012):文献号: 64003. |
入库方式： OAI收割
来源：长春应用化学研究所
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